具有模式热响应行为的聚n -异丙基丙烯酰胺-粘土纳米复合水凝胶

Y. Maki, T. Dobashi
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引用次数: 1

摘要

采用光引发自由基聚合法制备了具有数百微米小图案的聚N -异丙基丙烯酰胺(PNIPA)-粘土纳米复合水凝胶(NC凝胶)。当温度高于其较低临界溶液温度(LCST)时,所得凝胶的辐照区比掩膜区变得更不透明,这表明在可拉伸和坚韧的pnipa -粘土NC凝胶中可以制备具有调制热响应行为的小图案。
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Poly (N-isopropylacrylamide)-Clay Nanocomposite Hydrogels with Patterned Thermo-Responsive Behavior
Poly ( N -isopropylacrylamide) (PNIPA)-clay nanocomposite hydrogels (NC gels) having small patterns of several hundred micrometers were prepared by photoinitiated radical polymerization with the use of a patterned photomask. The irradiated region of the obtained gels became more opaque than the masked region at temperatures above its lower critical solution temperature (LCST), indicating that the small patterns with modulated thermo-responsive behavior can be fabricated in the stretchable and tough PNIPA-clay NC gels.
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