{"title":"二[1,3-二(2-甲氧基苯基)三氮烯]-碘化铜的合成及晶体结构","authors":"M. K. Rofouei, Tahereh Hashempur","doi":"10.2116/ANALSCIX.24.X229","DOIUrl":null,"url":null,"abstract":"The crystal structure of [Cu2I2L2], L = 1,3-bis(2-methoxyphenyl)triazene was determined by X-ray diffraction. The complex crystallizes in the monoclinic system, space group P21/c with a = 9.0976(8), b = 12.4229(12), c = 14.4204(11)A, β = 106.582(3)°, V = 1562.0(2)A3, Z = 2. The structure was solved by the full-matrix least-squares on F2 and had a refined R value of 0.0245 for 3486 reflections (I > 2σ(I)). The Cu2I2 moiety is coordinated by two molecules of the ligand via azide nitrogen and oxygen from a methoxy group in a trigonal pyramidal geometry.","PeriodicalId":7796,"journal":{"name":"Analytical Sciences: X-ray Structure Analysis Online","volume":"38 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2008-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Synthesis and Crystal Structure of Bis[1,3-bis(2-methoxyphenyl)triazene]-copper(I) Iodide\",\"authors\":\"M. K. Rofouei, Tahereh Hashempur\",\"doi\":\"10.2116/ANALSCIX.24.X229\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The crystal structure of [Cu2I2L2], L = 1,3-bis(2-methoxyphenyl)triazene was determined by X-ray diffraction. The complex crystallizes in the monoclinic system, space group P21/c with a = 9.0976(8), b = 12.4229(12), c = 14.4204(11)A, β = 106.582(3)°, V = 1562.0(2)A3, Z = 2. The structure was solved by the full-matrix least-squares on F2 and had a refined R value of 0.0245 for 3486 reflections (I > 2σ(I)). The Cu2I2 moiety is coordinated by two molecules of the ligand via azide nitrogen and oxygen from a methoxy group in a trigonal pyramidal geometry.\",\"PeriodicalId\":7796,\"journal\":{\"name\":\"Analytical Sciences: X-ray Structure Analysis Online\",\"volume\":\"38 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2008-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Analytical Sciences: X-ray Structure Analysis Online\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.2116/ANALSCIX.24.X229\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Analytical Sciences: X-ray Structure Analysis Online","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2116/ANALSCIX.24.X229","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 1
摘要
用x射线衍射法测定了[Cu2I2L2]， L = 1,3-双(2-甲氧基苯基)三氮杂烯的晶体结构。该配合物在单斜晶系中结晶，空间群为P21/c, a = 9.0976(8)， b = 12.4229(12)， c = 14.4204(11) a， β = 106.582(3)°，V = 1562.0(2)A3, Z = 2。利用全矩阵最小二乘在F2上求解，得到3486次反射(I > 2σ(I))的精确R值为0.0245。Cu2I2部分由两个配体分子通过叠氮氮和甲氧基氧在三角锥体几何结构中配位。
Synthesis and Crystal Structure of Bis[1,3-bis(2-methoxyphenyl)triazene]-copper(I) Iodide
The crystal structure of [Cu2I2L2], L = 1,3-bis(2-methoxyphenyl)triazene was determined by X-ray diffraction. The complex crystallizes in the monoclinic system, space group P21/c with a = 9.0976(8), b = 12.4229(12), c = 14.4204(11)A, β = 106.582(3)°, V = 1562.0(2)A3, Z = 2. The structure was solved by the full-matrix least-squares on F2 and had a refined R value of 0.0245 for 3486 reflections (I > 2σ(I)). The Cu2I2 moiety is coordinated by two molecules of the ligand via azide nitrogen and oxygen from a methoxy group in a trigonal pyramidal geometry.
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