{"title":"三价稀土Sm离子掺杂PVA/PVP共混聚合物薄膜的结构和光致发光性能","authors":"C. Salma, B. H. Rudramadevi","doi":"10.1080/07315171.2022.2076464","DOIUrl":null,"url":null,"abstract":"Abstract Transparent polyvinyl alcohol (PVA)/polyvinylpyrrolidone (PVP) and various concentrations of Sm3+ ion-doped PVA/PVP blend-polymer films were prepared using the solution cast method. The structural properties were studied by using XRD and FTIR. Optical UV-Vis, photoluminescence, and decay studies were carried out for prepared PVA/PVP blend polymer films. The XRD confirms the structural change in PVA/PVP blend-polymer with the doping of Sm3+ ion. From FTIR, Sm3+ ion forms the complex formation within the PVA/PVP polymer structure. The allowed band gap decreased from 5 to 4.6 eV, and the refractive index increased from 2.4 to 2.45, increasing Sm3+ ion concentration. From the energy band gap, the bonding parameters ( and δ) were calculated to find the covalent/ionic bond nature of the prepared polymer films. The emission spectra were measured for Sm3+: PVA/PVP with the excitation of 402 nm wavelength (6H5/2→4F7/2). 4G5/2→ 6H7/2 shows maximum intensity at 0.4 wt % of Sm3+, and beyond concentration, quenching was noticed. It is observed from the decay curve that the lifetime of PVA/PVP samples doped with Sm3+ at all concentrations decreases with the increase of Sm3+ ion concentration. It was noticed from CIE chromaticity that Sm3+: PVA/PVP blend polymer films are more appropriate for enhancing reddish-orange photonic emission. Based on the above results, Sm3+: PVA/PVP blend polymer films are suitable for reddish-orange luminescent applications.","PeriodicalId":50451,"journal":{"name":"Ferroelectrics Letters Section","volume":"132 1","pages":"30 - 44"},"PeriodicalIF":1.3000,"publicationDate":"2022-05-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Structural and photoluminescence properties of a trivalent rare earth Sm ion-doped PVA/PVP blend polymer films\",\"authors\":\"C. Salma, B. H. Rudramadevi\",\"doi\":\"10.1080/07315171.2022.2076464\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract Transparent polyvinyl alcohol (PVA)/polyvinylpyrrolidone (PVP) and various concentrations of Sm3+ ion-doped PVA/PVP blend-polymer films were prepared using the solution cast method. The structural properties were studied by using XRD and FTIR. Optical UV-Vis, photoluminescence, and decay studies were carried out for prepared PVA/PVP blend polymer films. The XRD confirms the structural change in PVA/PVP blend-polymer with the doping of Sm3+ ion. From FTIR, Sm3+ ion forms the complex formation within the PVA/PVP polymer structure. The allowed band gap decreased from 5 to 4.6 eV, and the refractive index increased from 2.4 to 2.45, increasing Sm3+ ion concentration. From the energy band gap, the bonding parameters ( and δ) were calculated to find the covalent/ionic bond nature of the prepared polymer films. The emission spectra were measured for Sm3+: PVA/PVP with the excitation of 402 nm wavelength (6H5/2→4F7/2). 4G5/2→ 6H7/2 shows maximum intensity at 0.4 wt % of Sm3+, and beyond concentration, quenching was noticed. It is observed from the decay curve that the lifetime of PVA/PVP samples doped with Sm3+ at all concentrations decreases with the increase of Sm3+ ion concentration. It was noticed from CIE chromaticity that Sm3+: PVA/PVP blend polymer films are more appropriate for enhancing reddish-orange photonic emission. Based on the above results, Sm3+: PVA/PVP blend polymer films are suitable for reddish-orange luminescent applications.\",\"PeriodicalId\":50451,\"journal\":{\"name\":\"Ferroelectrics Letters Section\",\"volume\":\"132 1\",\"pages\":\"30 - 44\"},\"PeriodicalIF\":1.3000,\"publicationDate\":\"2022-05-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Ferroelectrics Letters Section\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://doi.org/10.1080/07315171.2022.2076464\",\"RegionNum\":4,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"PHYSICS, CONDENSED MATTER\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Ferroelectrics Letters Section","FirstCategoryId":"101","ListUrlMain":"https://doi.org/10.1080/07315171.2022.2076464","RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"PHYSICS, CONDENSED MATTER","Score":null,"Total":0}
Structural and photoluminescence properties of a trivalent rare earth Sm ion-doped PVA/PVP blend polymer films
Abstract Transparent polyvinyl alcohol (PVA)/polyvinylpyrrolidone (PVP) and various concentrations of Sm3+ ion-doped PVA/PVP blend-polymer films were prepared using the solution cast method. The structural properties were studied by using XRD and FTIR. Optical UV-Vis, photoluminescence, and decay studies were carried out for prepared PVA/PVP blend polymer films. The XRD confirms the structural change in PVA/PVP blend-polymer with the doping of Sm3+ ion. From FTIR, Sm3+ ion forms the complex formation within the PVA/PVP polymer structure. The allowed band gap decreased from 5 to 4.6 eV, and the refractive index increased from 2.4 to 2.45, increasing Sm3+ ion concentration. From the energy band gap, the bonding parameters ( and δ) were calculated to find the covalent/ionic bond nature of the prepared polymer films. The emission spectra were measured for Sm3+: PVA/PVP with the excitation of 402 nm wavelength (6H5/2→4F7/2). 4G5/2→ 6H7/2 shows maximum intensity at 0.4 wt % of Sm3+, and beyond concentration, quenching was noticed. It is observed from the decay curve that the lifetime of PVA/PVP samples doped with Sm3+ at all concentrations decreases with the increase of Sm3+ ion concentration. It was noticed from CIE chromaticity that Sm3+: PVA/PVP blend polymer films are more appropriate for enhancing reddish-orange photonic emission. Based on the above results, Sm3+: PVA/PVP blend polymer films are suitable for reddish-orange luminescent applications.
期刊介绍:
Ferroelectrics Letters is a separately published section of the international journal Ferroelectrics. Both sections publish theoretical, experimental and applied papers on ferroelectrics and related materials, including ferroelastics, ferroelectric ferromagnetics, electrooptics, piezoelectrics, pyroelectrics, nonlinear dielectrics, polymers and liquid crystals.
Ferroelectrics Letters permits the rapid publication of important, quality, short original papers on the theory, synthesis, properties and applications of ferroelectrics and related materials.