激光解吸质谱:机理与应用

R.J. Cotter, J.-C. Tabet
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引用次数: 55

摘要

传统的飞行时间质谱仪已适应于脉冲激光解吸。这种仪器配置可以进行“时间分辨”质谱的研究,即激光脉冲后的延迟质量分析。激光脉冲后形成的离子的能量扩散与时间有关。迄今为止,这使得激光解吸产生的离子聚焦达到3628amu。讨论了激光解吸的机理和该仪器结构的应用。
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Laser desorption mass spectrometry: Mechanisms and applications

A conventional time-of-flight mass spectrometer has been adapted for pulsed laser desorption. This instrumental configuration enables investigation of “time resolved” mass spectra, i.e. delayed mass analysis following the laser pulse. The energy spread of ions formed after the laser pulse is time dependent. To date this has enabled focussing of ions produced by laser desorption up to 3628 amu. Mechanisms of laser desorption and applications of this instrumental configuration are discussed.

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Editorial Subject index Author index High resolution accurate mass measurements of FAB-generated ions by use of peak matching and multichannel analyzer techniques. Secondary ion mass spectrometry of low-temperature solids
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