酸性介质中铜腐蚀的防护

Rosita Wati, S. Hadisaputra, D. Asnawati, D. Hermanto
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引用次数: 3

摘要

在1 M H2SO4介质中,以pinostrobin为缓蚀剂,采用失重法测试了铜的缓蚀效果。结果表明,添加pinostrobin缓蚀剂可以降低腐蚀速率。pinostrobin在铜表面吸附的热力学性质遵循Freundlich等温线。抑制过程是吸热的、自发的和物理吸收的。通过Ea、Î H值和Î S、Î G值证明了这一点,热力学研究表明Ea值< 80kj。mol-1, †H阳性,†S阳性,Î " G < -20 kJ.mol-1。
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Protection of copper corrosion in acidic medium using pinostrobin
The corrosion inhibition efficiency of copper was tested by the weight loss method in 1 M H2SO4 medium in the presence of pinostrobin as inhibitor. It shows that the addition of pinostrobin inhibitor reduce the corrosion rate. The nature of thermodynamic of pinostrobin adsorption on copper surfaces follows the Freundlich isotherm. The process of inhibition is endothermic, spontaneous and physisorption. It is proved by the Ea, ΔH and ΔS and ΔG values in which the thermodynamic studies show that the values of Ea < 80 kJ.mol-1, ∆H positive, ∆S positive, and ΔG < -20 kJ.mol-1.
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