钛酸钾电磁辐射吸收无机聚合物复合材料的设计

Q3 Environmental Science Tikrit Journal of Engineering Sciences Pub Date : 2023-01-01 DOI:10.21272/jes.2023.10(1).c1
V. Lebedev, D. Miroshnichenko, Bemgba Bevan Nyakuma, V. Moiseev, O. Shestopalov, S. V. Vyrovets
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引用次数: 0

摘要

研究了以钛酸钾为原料合成电磁辐射吸收无机高分子复合材料。所选的聚酰胺6和聚钛酸钾材料含有TiО2、K2СО3和电荷烧结得到的KCl。结果表明,烧结产物对聚酰胺6进行改性后,形成了含有不同相K2O × 2TiO2、K2O × 4TiO2和K2O × 6TiO2的聚钛酸钾细粉,提高了聚酰胺6的强度性能。随着钛酸钾(PTT)合成的增加,K2O × 2TiO2 - K2O × 4TiO2 - K2O × 6TiO2由二钛酸钾逐渐过渡到六钛酸钾。聚钛酸钾的最佳质量分数为20%以上。为了充分保证聚钛酸钾聚酰胺6填充的补强效果,需要使用晶须K2O × 6TiO2,可通过非晶电荷烧结产物的附加结晶来收集晶须。通过设计等回归的实验统计数学模型,对无机高分子复合材料电磁辐射吸收性能进行了PTT数学优化。
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Design of Inorganic Polymer Composites for Electromagnetic Radiation Absorption Using Potassium Titanates
This paper investigated the synthesis of inorganic polymer composites for electromagnetic radiation absorption using potassium titanates. The selected polyamide 6 and potassium polytitanate materials contain TiО2, K2СО3, and KCl obtained by charge sintering. Results showed that modification of polyamide 6 with sintering products in the form of a fine powder of potassium polytitanate that contains different phases K2O × 2TiO2, K2O × 4TiO2, and K2O × 6TiO2 which increased their strength properties. With increased potassium titanates (PTT) synthesis, a gradual transition from di to potassium hexatitanates occurs K2O × 2TiO2 – K2O × 4TiO2 – K2O × 6TiO2. The optimal content of potassium polytitanate was over 20 % by mass. To fully ensure the reinforcing effect due to the filling of potassium polytitanate polyamide 6, it is necessary to use whiskers K2O × 6TiO2, which can be collected by the additional crystallization of the amorphous charge sintering product. By designing experimental-statistical mathematical models in equal regressions, mathematical optimization of inorganic polymer composites for electromagnetic radiation absorption using PTT was carried out.
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CiteScore
1.50
自引率
0.00%
发文量
56
审稿时长
8 weeks
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