有机-金属和有机-有机界面的高级表征:从光电子能谱数据到能级图

IF 2.9 4区 物理与天体物理 Q2 OPTICS Journal of Nonlinear Optical Physics & Materials Pub Date : 2022-11-02 DOI:10.1088/2515-7639/ac9f6f
Qi Wang, Jiacheng Yang, A. Gerlach, F. Schreiber, S. Duhm
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引用次数: 7

摘要

有机-金属和有机-有机界面几乎占据了所有有机光电应用的功能,而能级对准对器件性能尤为重要。通常,能级排列是简单地通过金属功函数、电离能和有机材料的电子亲和力来估计的。然而,各种界面效应,如推回、镜像力(也称为屏蔽)、电子极化或电荷转移都会影响能级排列。我们对银(111)上的铜-十六氟酞菁(F16CuPc)和钛-酞菁(TiOPc)薄膜进行了x射线和紫外光电子能谱(XPS和UPS)测量,并使用TiOPc双层将F16CuPc层与金属衬底解耦。即使我们的结构表征良好的模型界面和真空升华样品的逐步制备,真空能级和能级位移的精确分配仍然具有挑战性。然而,我们的结果为有机-金属和有机-有机界面的XPS和UPS数据的解释提供了指导。
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Advanced characterization of organic–metal and organic–organic interfaces: from photoelectron spectroscopy data to energy-level diagrams
Organic–metal and organic–organic interfaces account for the functionality of virtually all organic optoelectronic applications and the energy-level alignment is of particular importance for device performance. Often the energy-level alignment is simply estimated by metal work functions and ionization energies and electron affinities of the organic materials. However, various interfacial effects such as push back, mirror forces (also known as screening), electronic polarization or charge transfer affect the energy-level alignment. We perform x-ray and ultraviolet photoelectron spectroscopy (XPS and UPS) measurements on copper-hexadecafluorophthalocyanine (F16CuPc) and titanyl-phthalocyanine (TiOPc) thin films on Ag(111) and use TiOPc bilayers to decouple F16CuPc layers from the metal substrate. Even for our structurally well-characterized model interfaces and by stepwise preparation of vacuum-sublimed samples, a precise assignment of vacuum-level and energy-level shifts remains challenging. Nevertheless, our results provide guidelines for the interpretation of XPS and UPS data of organic–metal and organic–organic interfaces.
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来源期刊
CiteScore
3.00
自引率
48.10%
发文量
53
审稿时长
3 months
期刊介绍: This journal is devoted to the rapidly advancing research and development in the field of nonlinear interactions of light with matter. Topics of interest include, but are not limited to, nonlinear optical materials, metamaterials and plasmonics, nano-photonic structures, stimulated scatterings, harmonic generations, wave mixing, real time holography, guided waves and solitons, bistabilities, instabilities and nonlinear dynamics, and their applications in laser and coherent lightwave amplification, guiding, switching, modulation, communication and information processing. Original papers, comprehensive reviews and rapid communications reporting original theories and observations are sought for in these and related areas. This journal will also publish proceedings of important international meetings and workshops. It is intended for graduate students, scientists and researchers in academic, industrial and government research institutions.
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