电沉积法去除污染土壤中的Ra-226

Rana Abd El Wahab, A. M. El Shershabe, M. R. E. E. Din, A. Taha
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摘要

本研究的目的是从位于埃及西部沙漠的一家石油公司收集的污染土壤样品中去除Ra-226。在石油公司内干蒸发池不同位置的蒸发池底部采集了5个土壤样品(S-1、S-2、S-3、S-4、S-5)。用超纯锗探测器(HPGe)与MCA连接,测定了Ra-226的活度浓度。电沉积技术是用电流作用在导电材料上,使其浸入含有金属盐的溶液中,从而产生原位金属涂层。在溶液中加入化学试剂以提高污染物的去除效率,加入硝酸HNO3来提高Ra-226的溶解度。在这项研究中使用了三种不同的电极,分别由不锈钢、铝和铜制成。结果表明,采用铝杆时,Ra-226的去除率最高,达到73%。因此,从所获得的数据来看,使用铝杆去除Ra-226的电沉积技术可以用于石油工业污染土壤的修复或处理。
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Using of Electrodeposition Technique to remove Ra-226 from Contaminated soil
The aim of this study was to remove Ra-226 from the contaminated soil samples which collected from one of oil company located at western desert of Egypt. Five soil samples (S-1, S-2, S-3,S-4,S-5) were collected from the bottom of evaporation pond from different positions of dry evaporation pond inside the oil  company. The activity concentration of Ra-226 measured by using the Hyper Pure Germanium  detector (HPGe) connected to MCA . Electrodeposition  technique was used  to produce in situ metallic coatings by the action of an electric current on a conductive material immersed in a solution containing a salt of the metal to be deposited. Chemical agents added to the solution to increase the efficiency of contaminant removal  nitric acid HNO3 was added to improve the solubility of Ra-226. Three different  electrods made from stainless steel, aluminum and cupper poles  were used in this study. The data obtained showed that the highest removal  percentage of the Ra-226 found to be 73% when the aluminum pole was used. Therefore, from the obtained data, it is clear that the electrodeposition technique using aluminum poles for removal of Ra-226 can be used for remediation or treatment contaminated soil produced from oil industry.
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