{"title":"不稳定β-二酮酸铝(III)对映异构化的直接测定","authors":"Berardo Jurado, C. Springer","doi":"10.1039/C29710000085","DOIUrl":null,"url":null,"abstract":"Dynamic n.m.r. studies of tris-(2,6-dimethylheptane-3,5-dionato)aluminium(III), and bis(pentane-2,4-dionato)-(2,6-dimethylheptane-3,5-dionato)aluminium(III) give proof of the rapid enantiomerization of these complexes.","PeriodicalId":17278,"journal":{"name":"Journal of The Chemical Society D: Chemical Communications","volume":"10 1","pages":"85-87"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"9","resultStr":"{\"title\":\"Direct measurement of enantiomerization of labile aluminium(III)β-diketonates\",\"authors\":\"Berardo Jurado, C. Springer\",\"doi\":\"10.1039/C29710000085\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Dynamic n.m.r. studies of tris-(2,6-dimethylheptane-3,5-dionato)aluminium(III), and bis(pentane-2,4-dionato)-(2,6-dimethylheptane-3,5-dionato)aluminium(III) give proof of the rapid enantiomerization of these complexes.\",\"PeriodicalId\":17278,\"journal\":{\"name\":\"Journal of The Chemical Society D: Chemical Communications\",\"volume\":\"10 1\",\"pages\":\"85-87\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"9\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society D: Chemical Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/C29710000085\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society D: Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C29710000085","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Direct measurement of enantiomerization of labile aluminium(III)β-diketonates
Dynamic n.m.r. studies of tris-(2,6-dimethylheptane-3,5-dionato)aluminium(III), and bis(pentane-2,4-dionato)-(2,6-dimethylheptane-3,5-dionato)aluminium(III) give proof of the rapid enantiomerization of these complexes.
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