{"title":"Ni2P-O/MCM-41催化剂上苯并呋喃加氢脱氧反应性及动力学研究","authors":"Xueya Dai, Huaihui Song, Hualin Song, Jing Gong, Feng Li, Yanxiu Liu","doi":"10.1177/1468678319825909","DOIUrl":null,"url":null,"abstract":"A nickel phosphide hydrodeoxygenation catalyst (Ni2P-O/MCM-41) was prepared using a new synthetic method. The as-prepared catalyst was evaluated in the hydrodeoxygenation of benzofuran, and the effects of reaction temperature, pressure, and the H2/liquid ratio were investigated. A pseudo first-order model was employed to describe the reaction kinetics of benzofuran hydrodeoxygenation over the Ni2P-O/MCM-41 catalyst. The reaction rate constants (k1–k5) at different temperatures were determined according to this model. At 533 K, the conversion of 2-ethylphenol in to ethylbenzene began to increase dramatically, and the yield of O-free product, ethylcyclohexane, started to increase rapidly. At 573 K, 3.0 MPa, and a H2/liquid ratio of 500 (V/V), the conversion of benzofuran over Ni2P-O/MCM-41 reached 93%, and the combined yield of O-free products was 91%. Contact time analysis indicated that demethylation was not favored over the Ni2P-O/MCM-41 catalyst.","PeriodicalId":20859,"journal":{"name":"Progress in Reaction Kinetics and Mechanism","volume":"29 1","pages":"307 - 315"},"PeriodicalIF":2.1000,"publicationDate":"2019-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":"{\"title\":\"Reactivity and kinetic studies of benzofuran hydrodeoxygenation over a Ni2P-O/MCM-41 catalyst\",\"authors\":\"Xueya Dai, Huaihui Song, Hualin Song, Jing Gong, Feng Li, Yanxiu Liu\",\"doi\":\"10.1177/1468678319825909\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A nickel phosphide hydrodeoxygenation catalyst (Ni2P-O/MCM-41) was prepared using a new synthetic method. The as-prepared catalyst was evaluated in the hydrodeoxygenation of benzofuran, and the effects of reaction temperature, pressure, and the H2/liquid ratio were investigated. A pseudo first-order model was employed to describe the reaction kinetics of benzofuran hydrodeoxygenation over the Ni2P-O/MCM-41 catalyst. The reaction rate constants (k1–k5) at different temperatures were determined according to this model. At 533 K, the conversion of 2-ethylphenol in to ethylbenzene began to increase dramatically, and the yield of O-free product, ethylcyclohexane, started to increase rapidly. At 573 K, 3.0 MPa, and a H2/liquid ratio of 500 (V/V), the conversion of benzofuran over Ni2P-O/MCM-41 reached 93%, and the combined yield of O-free products was 91%. Contact time analysis indicated that demethylation was not favored over the Ni2P-O/MCM-41 catalyst.\",\"PeriodicalId\":20859,\"journal\":{\"name\":\"Progress in Reaction Kinetics and Mechanism\",\"volume\":\"29 1\",\"pages\":\"307 - 315\"},\"PeriodicalIF\":2.1000,\"publicationDate\":\"2019-07-24\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Progress in Reaction Kinetics and Mechanism\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1177/1468678319825909\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Progress in Reaction Kinetics and Mechanism","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1177/1468678319825909","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 2
摘要
采用新的合成方法制备了磷化镍加氢脱氧催化剂Ni2P-O/MCM-41。考察了所制备的催化剂对苯并呋喃加氢脱氧反应的影响,考察了反应温度、反应压力和H2/液比对催化剂加氢脱氧反应的影响。采用拟一阶模型描述了Ni2P-O/MCM-41催化剂上苯并呋喃加氢脱氧反应动力学。根据该模型确定了不同温度下的反应速率常数k1-k5。在533 K时,2-乙基苯酚in生成乙苯的转化率开始急剧提高,无o产物乙基环己烷的收率开始迅速提高。在573 K、3.0 MPa、H2/液比为500 (V/V)的条件下,ni2o - o /MCM-41对苯并呋喃的转化率达到93%,无o产物的总收率为91%。接触时间分析表明,Ni2P-O/MCM-41催化剂不有利于去甲基化。
Reactivity and kinetic studies of benzofuran hydrodeoxygenation over a Ni2P-O/MCM-41 catalyst
A nickel phosphide hydrodeoxygenation catalyst (Ni2P-O/MCM-41) was prepared using a new synthetic method. The as-prepared catalyst was evaluated in the hydrodeoxygenation of benzofuran, and the effects of reaction temperature, pressure, and the H2/liquid ratio were investigated. A pseudo first-order model was employed to describe the reaction kinetics of benzofuran hydrodeoxygenation over the Ni2P-O/MCM-41 catalyst. The reaction rate constants (k1–k5) at different temperatures were determined according to this model. At 533 K, the conversion of 2-ethylphenol in to ethylbenzene began to increase dramatically, and the yield of O-free product, ethylcyclohexane, started to increase rapidly. At 573 K, 3.0 MPa, and a H2/liquid ratio of 500 (V/V), the conversion of benzofuran over Ni2P-O/MCM-41 reached 93%, and the combined yield of O-free products was 91%. Contact time analysis indicated that demethylation was not favored over the Ni2P-O/MCM-41 catalyst.