纳米多孔活性炭在超级电容器中的合成及应用

A. Volperts, G. Dobele, J. Ozoliņš, Ņ. Mironova-Ulmane
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引用次数: 4

摘要

研究了热催化合成对微孔碳木基材料多孔结构的形成和性能的影响。研究发现,提高活化温度和碱活化剂的添加比例不仅可以控制总孔隙体积,还可以控制微孔和中孔比例。给出了合成碳材料作为超级电容器电极的试验结果,以及碳材料的多孔结构特性对电极工作特性的影响。结果表明:活化温度从600℃升高到800℃,导致多孔结构中介孔的比例增加;这会对超级电容的电池容量产生负面影响。研究发现,低温活化是制备超级电容器电极用活性炭最可行的方法。
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Synthesis and Application of Nanoporous Activated Carbon in Supercapacitors
Influence of the thermocatalytical synthesis on the formation of the porous structure and the properties of microporous carbon wood-based materials was shown. It was found that increase of activation temperature and addition ratio of alkali activator can be used to control not only total pore volume, but also micropore and mesopore proportion. The results of tests on the synthesized carbon materials as electrodes in supercapacitors are shown, as well as the influence of properties of the porous structure of carbon materials on working characteristics of electrodes. It was shown that the increase of activation temperature from 600 °C to 800 °C led to an increased proportion of mesopores in the porous structure; this negatively influencen the cell capacity of the supercapacitor. It was found that the most feasible way of production of activated cabons for the use as electrodes in supercapacitors with sulphuric acid-based electrolyte is low-temperature activation.
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