{"title":"密闭随机飞行聚物溶液:排除微孔和分布在屏障附近","authors":"Edward F. Casassa","doi":"10.1002/polc.5070720120","DOIUrl":null,"url":null,"abstract":"<p>The statistical basis of the entropic repulsion of dissolved random-flight polymer chains from impenetrable passive barriers is described. The application of these ideas to the partial exclusion of linear and branched polymer chains from micropores and to the polymer concentration profile near a barrier is reviewed with emphasis on the mean projection of the chain as a measure of the exclusion effect.</p>","PeriodicalId":16867,"journal":{"name":"Journal of Polymer Science: Polymer Symposia","volume":"72 1","pages":"151-160"},"PeriodicalIF":0.0000,"publicationDate":"1985-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1002/polc.5070720120","citationCount":"2","resultStr":"{\"title\":\"Confinedrandom-flightpolymerchainsinsolution: exclusion from micropores and distribution near barriers\",\"authors\":\"Edward F. Casassa\",\"doi\":\"10.1002/polc.5070720120\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The statistical basis of the entropic repulsion of dissolved random-flight polymer chains from impenetrable passive barriers is described. The application of these ideas to the partial exclusion of linear and branched polymer chains from micropores and to the polymer concentration profile near a barrier is reviewed with emphasis on the mean projection of the chain as a measure of the exclusion effect.</p>\",\"PeriodicalId\":16867,\"journal\":{\"name\":\"Journal of Polymer Science: Polymer Symposia\",\"volume\":\"72 1\",\"pages\":\"151-160\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1985-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1002/polc.5070720120\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Polymer Science: Polymer Symposia\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/polc.5070720120\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Polymer Science: Polymer Symposia","FirstCategoryId":"1085","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/polc.5070720120","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Confinedrandom-flightpolymerchainsinsolution: exclusion from micropores and distribution near barriers
The statistical basis of the entropic repulsion of dissolved random-flight polymer chains from impenetrable passive barriers is described. The application of these ideas to the partial exclusion of linear and branched polymer chains from micropores and to the polymer concentration profile near a barrier is reviewed with emphasis on the mean projection of the chain as a measure of the exclusion effect.
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