废铝箔混浊水处理中明矾结晶的合成及评价

O. H. Olabimtan, Oluyinka O Akinlotan, Joyce Omohu, M. K. Ukpong, Bayo H Yekeen
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摘要

废铝箔的处理是一个重要的环境问题,由于其不可生物降解的性质和潜在的污染周围的生态系统。本研究以废铝箔为原料合成明矾晶体,并评价其作为水处理的有效吸附剂的潜力。该合成工艺是将粉碎的铝箔与硫酸和氢氧化钠反应生成氢氧化铝,然后通过沉淀反应转化为明矾晶体。化学试验证实了明矾溶液和固体明矾晶体中存在不同的离子。试验表明,硫酸盐离子、钾离子和铝离子的存在。此外,本研究还考察了不同剂量(10 ~ 100 mg/l)明矾对水中除浊(三次)的影响,其中增加明矾的剂量会导致除浊的增加,但超过某一点,除浊的边际增加就会减少。通过使用二次关系来模拟浊度去除和明矾用量之间的非线性关系,确定了40-50 mg/L左右的用量是实现有效除浊和成本效益使用明矾之间平衡的最佳用量。该研究表明,废铝箔是一种合成明矾晶体的宝贵资源,可作为水处理的有效吸附剂。利用废料合成增值产品不仅有助于减少环境污染,而且有助于可持续技术的发展。本研究的结果对开发具有成本效益和环境可持续性的水处理解决方案具有重要意义。
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Synthesis and Evaluation of Alum Crystals from Waste Aluminum Foils in Turbid Water Treatment
The disposal of waste aluminum foil is a significant environmental concern due to its non-biodegradable nature and potential to contaminate the surrounding ecosystem. In this study, we synthesized alum crystals from waste aluminum foil and evaluated their potential as an effective adsorbent for water treatment. The synthesis process involved the reaction of crushed aluminum foil with sulfuric acid and sodium hydroxide to form aluminum hydroxide, which was then converted to alum crystals through a precipitation reaction. Chemical tests were conducted to confirm the presence of different ions in alum solution and solid alum crystals. The tests showed the presence of sulfate ions, potassium ions, and aluminum ions. Additionally, the study examined the effect of different dosages (10 to 100 mg/l) of alum on turbidity removal (triplicate) in water, where increasing the alum dosage led to an increase in turbidity removal, but beyond a certain point, the marginal increase in turbidity removal diminished. A dosage of around 40–50 mg/L was established as optimal for achieving a balance between effective turbidity removal and cost-effective use of alum, using a quadratic relationship to model a non-linear relationship between turbidity removal and alum dosage. This study demonstrates the potential of waste aluminum foil as a valuable resource for the synthesis of alum crystals, which can be used as an effective adsorbent for water treatment. Using waste materials for the synthesis of value-added products not only helps reduce environmental pollution but also contributes to the development of sustainable technologies. The results of this study have significant implications for the development of cost-effective and environmentally sustainable solutions for water treatment.
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