纳米氧化铁对废水污染粘土工程行为的修复趋势:实验研究

S. V. Mojtahed Sistani, H. Negahdar, F. Bamoharram, M. Shakeri
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引用次数: 1

摘要

城市污水污染土壤是城市中常见的一种污染类型,除对环境造成破坏外,还对土壤工程参数产生重大影响。研究了城市污水对土壤力学行为和粘土微观结构的影响,探讨了氧化铁纳米颗粒对污染土壤修复趋势的影响。为此,对含20%、60%和100%废水的污染样品进行了1个月、3个月和5个月的无侧限抗压强度(UCS)、崩塌和SEM分析测试,并对含0.5-4%纳米氧化铁的污染土壤进行了处理。结果表明,废水降低了粘土的抗剪强度,且随污染百分比的增加和污染时间的延长,降低的趋势增大。100%废水污染土壤的UCS在污染5个月后下降了49%。此外,废水在土壤中造成土壤塌陷5个月后。SEM图像显示,污染后粘土结构凝结,孔隙比天然土增大。改良阶段结果表明,在污染土壤中添加纳米氧化铁,抗剪强度显著提高,纳米氧化铁的最佳添加量为3%,单抗强度提高105.2%。随着纳米氧化铁含量的增加,污染土壤塌陷指数的强度减小。在最佳情况下,土壤最终应变比污染土壤降低43.4%。因此,建议利用纳米氧化铁来改善污染粘土的工程性能。
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Remediation Trend of Engineering Behavior of Wastewater Contaminated Clay Using Iron Nano Oxide: Experimental Studies
Soil polluted with urban wastewater due to defect of wastewater disposal and leakage from wastewater channels is a common type of pollution in urban areas which in addition to environmental damage, has significant effects on soil engineering parameters. In present study, effects of municipal wastewater on mechanical behavior of soil and clay microstructure was studied, and then effects of iron oxide nanoparticles on remediation trend of contaminated soil was investigated. To achieve this, unconfined compressive strength (UCS), collapse and SEM analysis tests were performed on contaminated samples containing 20%, 60% and 100% wastewater at 1, 3 and 5 months and also on contaminated soil remidiated with 0.5-4% Iron nano oxide. Results showed that wastewater reduces shear strength of clay and this decreasing trend increases with increasing percentage and contamination duration. UCS of soil contaminated with 100% wastewater decreased by 49% after 5 months of contamination. Also, wastewater in the soil caused to soil collapse after 5 months . SEM images showed the clay structure became clotted after contamination and soil pores increased compared to natural soil. Improvement phase results showed that by addition of Iron nano oxide to contaminated soil, shear strength significantly increased, and optimal percentage of Iron nano oxide was 3% in which UCS increased by 105.2%. By increasing the percentage of Iron nanoxide, intensity of collapse index of contaminated soil decreases. Best case senario, final strain of soil decreases by 43.4% compared to contaminated soil. Therefore, utilizing Iron nanooxide is recommended to improve engineering behavior of contaminated clay.
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