{"title":"第四章。碱性土基催化剂的二级(无机Si-H /静电C-F)相互作用","authors":"Y. Sarazin, J. Carpentier","doi":"10.1039/9781788016490-00094","DOIUrl":null,"url":null,"abstract":"The design and implementation of a selection of homogeneous alkaline earth (Ae) catalysts and precatalysts for hydroamination and hydrophosphination of olefins and for ring-opening polymerization of cyclic esters are surveyed. Emphasis is placed on the three large elements calcium, strontium and barium. The role of Ae⋯H–Si and Ae⋯F–C noncovalent interactions in the stabilization of (pre)catalysts is highlighted.","PeriodicalId":10054,"journal":{"name":"Catalysis Series","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2019-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"CHAPTER 4. Secondary (Agostic Si–H/Electrostatic C–F) Interactions in Alkaline Earth-based Catalysts\",\"authors\":\"Y. Sarazin, J. Carpentier\",\"doi\":\"10.1039/9781788016490-00094\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The design and implementation of a selection of homogeneous alkaline earth (Ae) catalysts and precatalysts for hydroamination and hydrophosphination of olefins and for ring-opening polymerization of cyclic esters are surveyed. Emphasis is placed on the three large elements calcium, strontium and barium. The role of Ae⋯H–Si and Ae⋯F–C noncovalent interactions in the stabilization of (pre)catalysts is highlighted.\",\"PeriodicalId\":10054,\"journal\":{\"name\":\"Catalysis Series\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2019-03-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Catalysis Series\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/9781788016490-00094\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Catalysis Series","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/9781788016490-00094","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The design and implementation of a selection of homogeneous alkaline earth (Ae) catalysts and precatalysts for hydroamination and hydrophosphination of olefins and for ring-opening polymerization of cyclic esters are surveyed. Emphasis is placed on the three large elements calcium, strontium and barium. The role of Ae⋯H–Si and Ae⋯F–C noncovalent interactions in the stabilization of (pre)catalysts is highlighted.
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