{"title":"碱性沸石:表征及其在吸附和催化中的应用","authors":"D. Barthomeuf","doi":"10.1080/01614949608006465","DOIUrl":null,"url":null,"abstract":"Abstract The presence of basic centers in some oxides has been recognized for a long time as being important in catalysis [1-4]. Usually both basic and acid sites exist simultaneously. The two centers may work independently or in a concerted way. For instance, in alcohol transformation, dehydration is favored on acidic sites and dehydrogenation on basic centers [3,5]. A large variety of materials are cited as having basic character. They include single-metal oxides (MgO, CaO, ZnO), supported alkali metals (Na/MgO, K/K2CO3), mixed-metal oxides (MgO-A12O3, ZnO-SiO2, MgO-TiO2), zeolites (X and Y saturated with alkaline cations of low electronegativity), hydrotalcite-type anionic clays, asbestoslike materials, carbon-supported basic catalysts, and basic organic resins. ∗ Present address: 16 rue Francois Gillet, 69003 Lyon, France.","PeriodicalId":50986,"journal":{"name":"Catalysis Reviews-Science and Engineering","volume":null,"pages":null},"PeriodicalIF":9.3000,"publicationDate":"1996-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"380","resultStr":"{\"title\":\"Basic zeolites : Characterization and uses in adsorption and catalysis\",\"authors\":\"D. Barthomeuf\",\"doi\":\"10.1080/01614949608006465\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract The presence of basic centers in some oxides has been recognized for a long time as being important in catalysis [1-4]. Usually both basic and acid sites exist simultaneously. The two centers may work independently or in a concerted way. For instance, in alcohol transformation, dehydration is favored on acidic sites and dehydrogenation on basic centers [3,5]. A large variety of materials are cited as having basic character. They include single-metal oxides (MgO, CaO, ZnO), supported alkali metals (Na/MgO, K/K2CO3), mixed-metal oxides (MgO-A12O3, ZnO-SiO2, MgO-TiO2), zeolites (X and Y saturated with alkaline cations of low electronegativity), hydrotalcite-type anionic clays, asbestoslike materials, carbon-supported basic catalysts, and basic organic resins. ∗ Present address: 16 rue Francois Gillet, 69003 Lyon, France.\",\"PeriodicalId\":50986,\"journal\":{\"name\":\"Catalysis Reviews-Science and Engineering\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":9.3000,\"publicationDate\":\"1996-11-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"380\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Catalysis Reviews-Science and Engineering\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1080/01614949608006465\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Catalysis Reviews-Science and Engineering","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1080/01614949608006465","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Basic zeolites : Characterization and uses in adsorption and catalysis
Abstract The presence of basic centers in some oxides has been recognized for a long time as being important in catalysis [1-4]. Usually both basic and acid sites exist simultaneously. The two centers may work independently or in a concerted way. For instance, in alcohol transformation, dehydration is favored on acidic sites and dehydrogenation on basic centers [3,5]. A large variety of materials are cited as having basic character. They include single-metal oxides (MgO, CaO, ZnO), supported alkali metals (Na/MgO, K/K2CO3), mixed-metal oxides (MgO-A12O3, ZnO-SiO2, MgO-TiO2), zeolites (X and Y saturated with alkaline cations of low electronegativity), hydrotalcite-type anionic clays, asbestoslike materials, carbon-supported basic catalysts, and basic organic resins. ∗ Present address: 16 rue Francois Gillet, 69003 Lyon, France.
期刊介绍：
Catalysis Reviews is dedicated to fostering interdisciplinary perspectives in catalytic science and engineering, catering to a global audience of industrial and academic researchers. This journal serves as a bridge between the realms of heterogeneous, homogeneous, and bio-catalysis, providing a crucial and critical evaluation of the current state of catalytic science and engineering. Published topics encompass advances in technology and theory, engineering and chemical aspects of catalytic reactions, reactor design, computer models, analytical tools, and statistical evaluations.
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