铁离子对臭氧氧化过程中天然有机物和THMFP还原的影响

Yeonwoo Kwak, Seulki Lee, G. Jang, Seong-ho Hong
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引用次数: 0

摘要

研究了不同铁浓度下臭氧氧化对地表水中天然有机物和三卤甲烷的去除效果。臭氧化受注射浓度的影响大于反应时间。臭氧氧化法对溶解有机碳的去除率随着亚铁浓度的增加而增加。铁离子浓度为6 mg/L时去除率最高。在臭氧浓度为2 mg/L的条件下,加入1 mg/L的亚铁,在反应开始时,由于亚铁在臭氧氧化过程中起到了生成羟基自由基的催化剂作用,比紫外吸光度迅速下降。随着臭氧浓度的增加,三卤甲烷生成势减小。当臭氧浓度为2 mg/L时,随着亚铁浓度的增加,三卤甲烷生成势先减小后增大。
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The effect of iron ions on the reducing of natural organic matter and THMFP in ozonation
This study focused on natural organic matter and trihalomethane removal by ozonation with various ferrous concentration in surface water. Ozonation is more affected by injection concentration than reaction time. dissolved organic carbon removal rates in ozonation increased with the increase in ferrous concentration. The highest removal was obtained at 6 mg/L of ferrous concentration. When 1 mg/L of ferrous was added with 2 mg/L of ozone concentration, it was found to be a rapid decrease in specific ultraviolet absorbance at the beginning of the reaction because ferrous acts as a catalyst for producing hydroxyl radical in ozonation. As ozone concentration increased, trihalomethane formation potential decreased. When 2 mg/L of ozone was injected, trihalomethane formation potential was shown to decrease and then increase again with the increase in ferrous concentration.
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