{"title":"1,1,1-三(二乙基)丙烷经arachno-CB4(10)和nido-C2B4(8)碳硼烷缩合成戊乙基-1,5-二碳-近戊硼烷(5)的缩合路线","authors":"R. Köster, R. Boese, B. Wrackmeyer, H. Schanz","doi":"10.1039/C39950001691","DOIUrl":null,"url":null,"abstract":"Diethyl(prop-1-ynyl)borane 1 reacts, in the presence of a large excess of tetraethyldiborane(6), to give the new substituted 1-carba-arachno-pentaborane(10)4 as the first intermediate which can be isolated; 4 rearranges via the nido-C2B4(8) carbaboranes A and Bto the known pentaethyl-1,5-dicarba-closo-pentaborane(5)5which is characterized by single crystal X-ray analysis.","PeriodicalId":17282,"journal":{"name":"Journal of The Chemical Society, Chemical Communications","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1995-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"14","resultStr":"{\"title\":\"Condensation route from 1,1,1-tris(diethylboryl)propane to pentaethyl-1,5-dicarba-closo-pentaborane(5)via arachno-CB4(10) and nido-C2B4(8) carbaboranes\",\"authors\":\"R. Köster, R. Boese, B. Wrackmeyer, H. Schanz\",\"doi\":\"10.1039/C39950001691\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Diethyl(prop-1-ynyl)borane 1 reacts, in the presence of a large excess of tetraethyldiborane(6), to give the new substituted 1-carba-arachno-pentaborane(10)4 as the first intermediate which can be isolated; 4 rearranges via the nido-C2B4(8) carbaboranes A and Bto the known pentaethyl-1,5-dicarba-closo-pentaborane(5)5which is characterized by single crystal X-ray analysis.\",\"PeriodicalId\":17282,\"journal\":{\"name\":\"Journal of The Chemical Society, Chemical Communications\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1995-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"14\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society, Chemical Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/C39950001691\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society, Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C39950001691","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Condensation route from 1,1,1-tris(diethylboryl)propane to pentaethyl-1,5-dicarba-closo-pentaborane(5)via arachno-CB4(10) and nido-C2B4(8) carbaboranes
Diethyl(prop-1-ynyl)borane 1 reacts, in the presence of a large excess of tetraethyldiborane(6), to give the new substituted 1-carba-arachno-pentaborane(10)4 as the first intermediate which can be isolated; 4 rearranges via the nido-C2B4(8) carbaboranes A and Bto the known pentaethyl-1,5-dicarba-closo-pentaborane(5)5which is characterized by single crystal X-ray analysis.
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