Danishefsky二烯在不对称氧- diels - alder反应中的应用

Q2 Chemistry Tetrahedron, asymmetry Pub Date : 2017-11-15 DOI:10.1016/j.tetasy.2017.10.030

Afsaneh Taheri kal Koshvandi, Majid M. Heravi

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引用次数: 18

摘要

重点介绍了丹尼舍夫斯基二烯在催化不对称杂diels - alder (AHDA)反应中的应用，特别是在与合适的亲二烯试剂的不对称氧- diels - alder (AOxo-DA)反应中的应用，包括催化剂的制备，并从机理的角度进行了讨论。丹尼舍夫斯基二烯是合成二氢吡啶酮、二氢吡啶酮和二氢吡喃等具有光学活性的六元环的有效化合物。由于整个主题的范围很广，我们将自己限制在Danishefsky的二烯与羰基化合物(醛，酮和1,2-二羰基化合物)在不对称氧- diels - alder (AOxo-DA)反应中的应用的最新进展。

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Applications of Danishefsky’s dienes in asymmetric Oxo-Diels-Alder reactions

Applications of Danishefsky’s dienes in catalytic asymmetric hetero-Diels-Alder (AHDA) reactions or specifically, their asymmetric Oxo-Diels-Alder (AOxo-DA) reactions with appropriate dienophiles are highlighted in detail, including the preparation of catalysts with discussion from a mechanistic points of view. Danishefsky’s dienes are effective and useful compounds for the synthesis of optically active six-membered rings such as dihydropyrones, dihydropyridones and dihydropyrans. Due to the broad range of the overall subject, we have limited ourselves, to the recent developments in the utility of Danishefsky’s dienes in the reaction with carbonyl compounds (aldehydes, ketones and 1,2-dicarbonyl compounds) in asymmetric Oxo-Diels-Alder (AOxo-DA) reactions.

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来源期刊

Tetrahedron, asymmetry 化学-无机化学与核化学

CiteScore

4.70

自引率

0.00%

发文量

审稿时长

1 months

期刊介绍： Cessation. Tetrahedron: Asymmetry presents experimental or theoretical research results of outstanding significance and timeliness on asymmetry in organic, inorganic, organometallic and physical chemistry, as well as its application to related disciplines, especially bio-organic chemistry. The journal publishes critical reviews, original research articles and preliminary communications dealing with all aspects of the chemical, physical and theoretical properties of non-racemic organic and inorganic materials and processes. Topics relevant to the journal include: the physico-chemical and biological properties of enantiomers; strategies and methodologies of asymmetric synthesis; resolution; chirality recognition and enhancement; analytical techniques for assessing enantiomeric purity and the unambiguous determination of absolute configuration; and molecular graphics and modelling methods for interpreting and predicting asymmetric phenomena. Papers describing the synthesis or properties of non-racemic molecules will be required to include a separate statement in the form of a Stereochemistry Abstract, for publication in the same issue, of the criteria used for the assignment of configuration and enantiomeric purity.

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