反向胶束电动毛细管色谱、静压流动进样和扩散进样的实验研究

K. Ghowsi, Hosein Ghowsi
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引用次数: 0

摘要

Dunn, Hankins和Ghowsi观察到毛细管电泳中离子的迁移方向与电渗透相反,离子的移动速度比流动速度快,最终将它们分离并到达检测器。对于对二甲苯和甲苯的分离,一种类似形式的电动色谱被称为反方向MECC(胶束电动毛细管色谱)。在反方向胶束电动毛细管色谱中,探讨了进样时间对分离的影响。本文研究了流体静压注射和扩散注射。
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An Experimental Investigation on Reverse Direction Micellar Electrokinetic Capillary Chromatography, Hydrostatic Flow Injection and Diffusional Injection
Dunn, Hankins, and Ghowsi observed separation in the case where ions incapillary electrophoresis migrate in the opposite direction of electroosmosis and ions travel faster than flow, eventually separating them and reaching the detector.For the separation of p-xylene and toluene, a similar form of electrokinetic chromatography called reverse direction MECC has been developed (micellar electrokinetic capillary chromatography).In reverse direction micellar electrokinetic capillary chromatography, the influence of injection time on separation is explored. Hydrostatic and diffusion injection were investigated in this study.
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