关于非晶固体的刚性

M. Wyart
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引用次数: 243

摘要

我们对非晶系统在小长度尺度上的性质了解甚少,在小长度尺度上,连续的弹性描述就失效了。当我们考虑它们的振动和输运性质,或者力在这些固体中传播的方式时,这一点就很明显了。人们对它们坚硬的微观原因知之甚少。最近,数值研究发现弹性粒子的组合在压力消失的干扰阈值附近具有临界行为。在过渡时,这样的系统在任何长度尺度上都不表现为连续介质。当该系统被压缩时,可以观察到弹性模量、配位数以及振动模态密度的标度变化。在目前的工作中,我们从理论上推导了这些结果,并表明它们适用于各种系统,如颗粒物质和二氧化硅,但也适用于胶体玻璃。我们特别指出:(i)与普通固体相比,这些体系在低频下表现出大量的振动模式,在玻璃文献中称为“玻色子峰”。相应的模态与平面波有很大的不同,其频率与系统的配位有关;(ii)刚性是填料几何形状的非局部特性,其特征是长度尺度可以很大。对于弹性粒子,该长度在干扰过渡附近发散;(iii)对于排斥性体系,剪切模量可以比体积模量小得多。在干扰阈值附近计算相应的标度规律。最后,我们讨论了这些结果对玻璃化转变、输运和随机紧密堆积的几何形状的影响。
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On the rigidity of amorphous solids
We poorly understand the properties of amorphous systems at small length scales, where a continuous elastic description breaks down. This is apparent when one considers their vibrational and transport properties, or the way forces propagate in these solids. Little is known about the microscopic cause of their rigidity. Recently it has been observed numerically that an assembly of elastic particles has a critical behavior near the jamming threshold where the pressure vanishes. At the transition such a system does not behave as a continuous medium at any length scales. When this system is compressed, scaling is observed for the elastic moduli, the coordination number, but also for the density of vibrational modes. In the present work, we derive theoretically these results, and show that they apply to various systems such as granular matter and silica, but also to colloidal glasses. In particular we show that: (i) these systems present a large excess of vibrational modes at low frequency in comparison with normal solids, called the "boson peak" in the glass literature. The corresponding modes are very different from plane waves, and their frequency is related to the system coordination; (ii) rigidity is a non-local property of the packing geometry, characterized by a length scale which can be large. For elastic particles this length diverges near the jamming transition; (iii) for repulsive systems the shear modulus can be much smaller than the bulk modulus. We compute the corresponding scaling laws near the jamming threshold. Finally, we discuss the implications of these results for the glass transition, the transport, and the geometry of the random close packing.
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Annales De Physique
Annales De Physique 物理-物理:综合
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