灌木蔗皮粉对亚甲基蓝染料的吸附研究

C. K. Enenebeaku, N. J. Okorocha, U. E. Enenebeaku, B. Onyeachu
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引用次数: 11

摘要

通过分析接触时间、染料初始浓度、吸附剂用量、pH、温度等因素对单位质量吸附剂吸附亚甲基蓝染料量的影响,研究了亚甲基蓝染料在甘蔗皮粉上的吸附性能。接触时间为80 min时吸附效果最佳,超过80 min后吸附效果下降。随着染料初始浓度、温度和ph的增加,亚甲基蓝染料的吸附量增加,但随着吸附剂用量的增加,亚甲基蓝的吸附量减少;随着吸附剂用量的增加,吸附剂会发生貌似合理的结块和首选吸附位点的阻塞现象。染料的吸附机理服从Freundlich等温线。动力学研究表明,灌木树皮粉末吸附剂对亚甲基蓝的吸附符合二级反应动力学。采用傅里叶变换红外分光光度计和扫描电镜对吸附剂进行了表征。
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Adsorption of Methylene Blue Dye onto Bush Cane Bark Powder
The adsorption of methylene blue (MB) dye on bush cane bark powder has been studied by analyzing the effect of contact time, initial dye concentration, adsorbent dose, pH, and temperature on the amount of the MB dye adsorbed per unit mass of the bush cane bark powder adsorbent. An optimum adsorption could be achieved during 80 min contact time but, thereafter, decreased with contact time beyond 80 min. The adsorption of the methylene blue dye increased with increasing the initial dye concentration, temperature and pH. However, the amount of methylene blue adsorbed decreased with increasing the dosage of the adsorbent; a phenomenon attributed to a plausible agglomeration of the adsorbent and blocking of the preferred adsorption sites with increasing adsorbent dosage. The adsorption mechanism of the dye obeyed the Freundlich isotherm. Kinetic studies showed that the methylene blue adsorption onto bush cane bark powder adsorbent followed a second order reaction kinetics. The adsorbent was characterized by Fourier transform infra-red spectrophotometer and scanning electron microscope analysis.
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