fa、Kossou和Taabo(象牙海岸)水电站大坝中有机磷残留物对颚鱼(Chrysichthys nigrodigitatus, (lapacimc,(1803))的污染状况

Koukougnon Kouho Lydie, Ossehin Ambroise, Acho Yapi Fulgence, K. Mamadou, T. Sory
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摘要

本研究旨在确定fa、Kossou和Taabo水电站大坝中有机磷残留物对黑颌鱼(Chrysichthys nigrodigitatus)的污染程度。在八次采样活动中,从这三个水坝中采集了90条鱼。形成复合样品,每个样品代表两条鱼。共制备了45个复合样品。采用气相色谱-质谱联用技术(GC/MS)对鱼样品中农药残留进行检测。结果表明,3座大坝的平均有机磷总负荷为0.184 mg/kg。fafaal水电站在鱼类样本中的总负荷最高,为0.266 mg/kg,而Taabo水电站为0.197 mg/kg, Kossou水电站为0.089 mg/kg。甲基对硫磷的平均总浓度较高,为0.130±0.023 mg/kg。在3个水电站大坝的鱼类样本中,只有氯虫腈的总平均浓度为0.046±0.007 mg/kg。此外,鱼类样本中检测到的大部分分子浓度超过了农药的最大残留限量(MRLs),其值范围为0.01至0.05 mg/kg。
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Status of Contamination of the Jawfish (Chrysichthys nigrodigitatus, (Lapécède, (1803)) by Organophosphorus Residues in the Hydroelectric Dams of Faé, Kossou and Taabo (Ivory Coast)
The present study aims at determining the level of contamination of the jawfish (Chrysichthys nigrodigitatus) by organophosphate residues in the hydroelectric dams of Faé, Kossou and Taabo. Ninety (90) fish were collected from these three dams during eight sampling campaigns. Composite samples were formed, each for two fish. A total of forty-five (45) composite samples were formed. The detection of pesticide residues in the fish samples was determined by gas chromatography-mass spectrometer (GC/MS). The results show that the average total organophosphate residue load at the three dams is 0.184 mg/kg. The Faé hydroelectric scheme had the highest total load of 0.266 mg/kg in fish samples, compared to 0.197 mg/kg for Taabo and 0.089 mg/kg for the Kossou hydroelectric dam. The relatively high average total concentration is observed for parathion-methyl with a value of 0.130 ± 0.023 mg/kg. Chlorfenvinphos, with a total average concentration of 0.046 ± 0.007 mg/kg was the only molecule present in all the fish samples analyzed in the three hydroelectric dams. In addition, most of the molecules detected in the fish samples had concentrations that exceeded the Maximum Residue Limits (MRLs) for pesticides, whose values range from 0.01 to 0.05 mg/kg.
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