{"title":"由生成函数推导连续分子量分布","authors":"K.S. Whiteley, A. Garriga","doi":"10.1016/S1089-3156(00)00026-X","DOIUrl":null,"url":null,"abstract":"<div><p>A method described in the statistical literature for the numerical inversion of Laplace Transforms of real functions has been adapted for the derivation of molecular weight distributions from calculations of the generating function for a polymeric system. It has been shown that a third-order refinement is sufficiently accurate for molecular weight distributors broader than 4.0. This allows the calculations to be carried out with a precision of 16 decimal digits which is commonly used in Fortran. Where higher precision is available, the treatment is applicable to narrower MWDs.</p></div>","PeriodicalId":100309,"journal":{"name":"Computational and Theoretical Polymer Science","volume":"11 4","pages":"Pages 319-324"},"PeriodicalIF":0.0000,"publicationDate":"2001-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S1089-3156(00)00026-X","citationCount":"7","resultStr":"{\"title\":\"Derivation of continuous molecular weight distributions from the generating function\",\"authors\":\"K.S. Whiteley, A. Garriga\",\"doi\":\"10.1016/S1089-3156(00)00026-X\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>A method described in the statistical literature for the numerical inversion of Laplace Transforms of real functions has been adapted for the derivation of molecular weight distributions from calculations of the generating function for a polymeric system. It has been shown that a third-order refinement is sufficiently accurate for molecular weight distributors broader than 4.0. This allows the calculations to be carried out with a precision of 16 decimal digits which is commonly used in Fortran. Where higher precision is available, the treatment is applicable to narrower MWDs.</p></div>\",\"PeriodicalId\":100309,\"journal\":{\"name\":\"Computational and Theoretical Polymer Science\",\"volume\":\"11 4\",\"pages\":\"Pages 319-324\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2001-08-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/S1089-3156(00)00026-X\",\"citationCount\":\"7\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Computational and Theoretical Polymer Science\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S108931560000026X\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Computational and Theoretical Polymer Science","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S108931560000026X","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Derivation of continuous molecular weight distributions from the generating function
A method described in the statistical literature for the numerical inversion of Laplace Transforms of real functions has been adapted for the derivation of molecular weight distributions from calculations of the generating function for a polymeric system. It has been shown that a third-order refinement is sufficiently accurate for molecular weight distributors broader than 4.0. This allows the calculations to be carried out with a precision of 16 decimal digits which is commonly used in Fortran. Where higher precision is available, the treatment is applicable to narrower MWDs.