由生成函数推导连续分子量分布

K.S. Whiteley, A. Garriga
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引用次数: 7

摘要

统计文献中描述的实数函数的拉普拉斯变换的数值反演方法已被用于从聚合物体系的生成函数的计算中推导分子量分布。结果表明,对于大于4.0的分子量分布,三阶精化是足够精确的。这允许以16位十进制数字的精度进行计算,这在Fortran中是常用的。在精度更高的情况下,处理适用于更窄的mwd。
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Derivation of continuous molecular weight distributions from the generating function

A method described in the statistical literature for the numerical inversion of Laplace Transforms of real functions has been adapted for the derivation of molecular weight distributions from calculations of the generating function for a polymeric system. It has been shown that a third-order refinement is sufficiently accurate for molecular weight distributors broader than 4.0. This allows the calculations to be carried out with a precision of 16 decimal digits which is commonly used in Fortran. Where higher precision is available, the treatment is applicable to narrower MWDs.

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