{"title":"微波辐射对分子间和分子内Friedel-Crafts酰化反应的影响","authors":"Y. Okada, Arisa Fujitsu","doi":"10.4236/gsc.2020.101002","DOIUrl":null,"url":null,"abstract":"The effect of microwave irradiation on the intermolecular and \nintramolecular Friedel-Crafts \nacylation of aromatic compounds was investigated. Microwave irradiation had no \neffect on the intermolecular reaction but had an accelerating effect on the intramolecular \nreaction. This enhanced intramolecular reactivity that was attributed to the high \nprobability of close proximity between the reaction sites.","PeriodicalId":12770,"journal":{"name":"Green and Sustainable Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2020-01-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Microwave Irradiation Effect on Intermolecular and Intramolecular Friedel-Crafts Acylation Reaction\",\"authors\":\"Y. Okada, Arisa Fujitsu\",\"doi\":\"10.4236/gsc.2020.101002\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The effect of microwave irradiation on the intermolecular and \\nintramolecular Friedel-Crafts \\nacylation of aromatic compounds was investigated. Microwave irradiation had no \\neffect on the intermolecular reaction but had an accelerating effect on the intramolecular \\nreaction. This enhanced intramolecular reactivity that was attributed to the high \\nprobability of close proximity between the reaction sites.\",\"PeriodicalId\":12770,\"journal\":{\"name\":\"Green and Sustainable Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2020-01-21\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Green and Sustainable Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.4236/gsc.2020.101002\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Green and Sustainable Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.4236/gsc.2020.101002","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Microwave Irradiation Effect on Intermolecular and Intramolecular Friedel-Crafts Acylation Reaction
The effect of microwave irradiation on the intermolecular and
intramolecular Friedel-Crafts
acylation of aromatic compounds was investigated. Microwave irradiation had no
effect on the intermolecular reaction but had an accelerating effect on the intramolecular
reaction. This enhanced intramolecular reactivity that was attributed to the high
probability of close proximity between the reaction sites.
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