sbr -纳米氧化铝复合材料的合成、表征、环境性能及力学性能研究

R. Mankar, W. Gurnule
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引用次数: 3

摘要

由于纳米材料具有聚合物性质的适应性,橡胶或纳米氧化铝复合材料可能被认为是潜在的机械应用材料。采用乳液聚合法制备了橡胶纳米复合材料。为了获得更好的橡胶-填料相互作用,对其力学性能和耐环境性能进行了评价。研究了丁苯橡胶(SBR)纳米复合材料的拉曼光谱和力学性能,并在纳米氧化铝添加剂的视野下进行了研究。利用双辊磨机进行机械混合制备纳米复合材料。将纳米氧化铝颗粒悬浮液添加到SBR中,并对其耐磨性和光谱性能进行了综述。采用纳米氧化铝、2,2′-二硫铋、四甲基硫脲二硫化、N,N′-二苯基对苯二胺和SBR胶乳进行分析。采用乳液聚合法制备了SBR纳米复合材料。力学试验结果表明,抗拉强度、伸长率和抗撕裂性均有改善。磨损试验结果表明,由于纳米氧化铝颗粒具有良好的性能,可以提高SBR基体的耐磨性。与传统填料相比,填料的增强能力导致聚合物框架在极低填料负荷下的性能显著提升。在这项工作中,我们专注于拉曼光谱和机械性能,包括填料含量在低加载量。利用扫描电子显微镜(SEM)建立了复合橡胶纳米复合材料的收集思路。通过透射电镜研究了纳米颗粒对sbr -纳米氧化铝聚合物网络的影响。热重分析(TGA和DTA)也进行了检查。研究了耐臭氧性,以阐明裂纹萌生时试样表面的周期性观察。这些样本暴露的时间更长。研究了阻燃性,以测量火焰熄灭的难易程度,根据燃烧时间和火焰滴的存在,可能有四个等级。本研究重点研究了乳液聚合方法,该方法改善了橡胶纳米复合材料的耐环境性能,并增强了其热学和力学性能。
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Synthesis, Characterization, Environmental Properties and Mechanical Studies of SBR-Nano Aluminum Oxide Composites
Rubber or nano aluminum oxide composites may be considered as potential materials in mechanical applications because of the adaptability of polymer properties of nanometric substances. Rubber nano-composite is prepared by using the emulsion polymerization method. Mechanical properties and environmental resistance properties are evaluated for a better rubber-filler interaction. In this examination, the Raman spectroscopy and the mechanical properties of nanocomposites are based on Styrene-Butadiene rubber (SBR) and were explored within the sight of nano aluminum oxide additive. The nano-composites were prepared by mechanically mixing and utilizing two-roll mills. Nano aluminum oxide particle suspensions were added to SBR and the abrasion and spectral properties were overviewed. Nano aluminum oxide, 2, 2’- dithiobis, tetramethyl thiuram disulfide, N, N’- Diphenyl P- phenylenediamine and SBR latex were used for analysis. SBR nano-composite was obtained by using the emulsion polymerization method. Mechanical test outcomes demonstrated the improvement in tensile strength, elongation, and tear resistance. Abrasion test results demonstrated that nano aluminum oxide particles could improve the abrasion resistance of SBR matrix because of the good properties of nano aluminum oxide particles. The strengthening capacity of the fillers resulted in noteworthy upgrades in the properties of polymer framework at extremely low filler loadings when contrasted with conventional fillers. In this work, we concentrate on Raman spectroscopy and mechanical properties by including filler content within a low loading amount. The collection idea of the combined rubber nano-composite was built up by using scanning electron microscopy (SEM). The impact of nanoparticles in the polymer network has been assessed for the SBR-nano aluminum oxide from the TEM investigation. Thermogravimetric analysis (TGA and DTA) was also examined. Ozone resistance was studied to elucidate periodic observations of the surface of samples, which were made for crack initiation. The samples were exposed for a longer time. Flame resistance was studied to measure the ease of extinction of a flame and four ratings were possible, depending upon the burning time and the presence of flaming drips. The present study highlights the emulsion polymerization method, where the environmental resistance performance of rubber nano-composites is found to be improved and the thermal and mechanical properties are also enhanced.
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