{"title":"铑(II)羧化物","authors":"T. Ho, M. Fieser, L. Fieser, R. Danheiser, W. Roush, Janice Y. Smith","doi":"10.1002/9780471264194.fos08768.pub2","DOIUrl":null,"url":null,"abstract":"This article has no abstract. \n \nKeywords: \n \ncyclopropanation with alkyl diazoacetates; \ncyclopropenation; \nthiophenium ylides; \ncyclopropanation; \nβ-lactams; \nβ-keto esters from α-diazo-β-hydroxy esters; \nbuchner reaction; \ncyclopropanation of ; \n2-carbapenems; \nalkylation of β-lactams; \nintramolecular cycloaddition of a diazo ketone to a cyclopropene; \ncyclopentanones; \ncis-α,β-unsaturated esters; \nunsaturated ethers; \nδ-lactones; \nchiral cyclopentanones; \nintramolecular buchner reaction; \nhydroformylation; \nbenzyl ketones; \ncyclization-cycloaddition of an α-diazoacetophenone; \nchiral 3,3-disubstituted cyclopentanones; \nintramolecular C—H insertion; \noxepanes and oxocanes; \ncyclopropanation of furanyl diazo ketones; \nβ-lactams; \nα-silyl esters or ketones; \ndiazo ketone cyclization to hydroazulenones; \ncyclization/cycloaddition route to oxapolycycles; \n2,5-disubstituted 3(2H)-furanones; \nfurans; \ncarbenoid–monothiophthalimide coupling; \nrearrangement of N-nitrosoamides; \ntropones; \nreaction of α-diazo ketones with alkynes; \nsynthesis of (+)-griseofulvin (3); \nreaction of cyclic diazo-1,3-dicarbonyls with aryl heterocycles; \ntricyclic dihydropyrrolizines; \nreaction with cyclopropenes; \nα-alkoxy esters; \ninsertion into SiH bonds; \nheterocyclization; \nsilylformylation; \ncarbenoid insertions; \ncyclopropanation; \nheterocycles; \nconjugated ketenes; \nhydroformylation; \ncarbenoid insertions; \nrearrangements; \nfour-membered rings; \ndiheterobicycloalkanes; \n[3 + 2]cycloadditions; \nwolff rearrangement; \nthree-membered rings; \nfive-membered rings; \nC-H insertion; \nrearrangement; \n1-acetoxyazulenes; \ncoupling; \ntransylidation; \nbond insertion; \nbicyclization; \nbenzyl alcohols; \nN-sulfonylcarboxamides; \nisomerization; \narylation; \nCH Bond Insertion; \nNH Bond Insertion; \nNO Bond Insertion; \ncyclization; \nrhenium(VII) oxide; \nRh/alumina catalyst hydrogenation; \nrhodium - iron; \nrhodium(I) hexafluoroantimonate; \nruthenium(III) chloride hydrate","PeriodicalId":12135,"journal":{"name":"Fieser and Fieser's Reagents for Organic Synthesis","volume":"68 1","pages":"000-000"},"PeriodicalIF":0.0000,"publicationDate":"2017-02-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"5","resultStr":"{\"title\":\"Rhodium(II) carboxylates\",\"authors\":\"T. Ho, M. Fieser, L. Fieser, R. Danheiser, W. Roush, Janice Y. Smith\",\"doi\":\"10.1002/9780471264194.fos08768.pub2\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"This article has no abstract. \\n \\nKeywords: \\n \\ncyclopropanation with alkyl diazoacetates; \\ncyclopropenation; \\nthiophenium ylides; \\ncyclopropanation; \\nβ-lactams; \\nβ-keto esters from α-diazo-β-hydroxy esters; \\nbuchner reaction; \\ncyclopropanation of ; \\n2-carbapenems; \\nalkylation of β-lactams; \\nintramolecular cycloaddition of a diazo ketone to a cyclopropene; \\ncyclopentanones; \\ncis-α,β-unsaturated esters; \\nunsaturated ethers; \\nδ-lactones; \\nchiral cyclopentanones; \\nintramolecular buchner reaction; \\nhydroformylation; \\nbenzyl ketones; \\ncyclization-cycloaddition of an α-diazoacetophenone; \\nchiral 3,3-disubstituted cyclopentanones; \\nintramolecular C—H insertion; \\noxepanes and oxocanes; \\ncyclopropanation of furanyl diazo ketones; \\nβ-lactams; \\nα-silyl esters or ketones; \\ndiazo ketone cyclization to hydroazulenones; \\ncyclization/cycloaddition route to oxapolycycles; \\n2,5-disubstituted 3(2H)-furanones; \\nfurans; \\ncarbenoid–monothiophthalimide coupling; \\nrearrangement of N-nitrosoamides; \\ntropones; \\nreaction of α-diazo ketones with alkynes; \\nsynthesis of (+)-griseofulvin (3); \\nreaction of cyclic diazo-1,3-dicarbonyls with aryl heterocycles; \\ntricyclic dihydropyrrolizines; \\nreaction with cyclopropenes; \\nα-alkoxy esters; \\ninsertion into SiH bonds; \\nheterocyclization; \\nsilylformylation; \\ncarbenoid insertions; \\ncyclopropanation; \\nheterocycles; \\nconjugated ketenes; \\nhydroformylation; \\ncarbenoid insertions; \\nrearrangements; \\nfour-membered rings; \\ndiheterobicycloalkanes; \\n[3 + 2]cycloadditions; \\nwolff rearrangement; \\nthree-membered rings; \\nfive-membered rings; \\nC-H insertion; \\nrearrangement; \\n1-acetoxyazulenes; \\ncoupling; \\ntransylidation; \\nbond insertion; \\nbicyclization; \\nbenzyl alcohols; \\nN-sulfonylcarboxamides; \\nisomerization; \\narylation; \\nCH Bond Insertion; \\nNH Bond Insertion; \\nNO Bond Insertion; \\ncyclization; \\nrhenium(VII) oxide; \\nRh/alumina catalyst hydrogenation; \\nrhodium - iron; \\nrhodium(I) hexafluoroantimonate; \\nruthenium(III) chloride hydrate\",\"PeriodicalId\":12135,\"journal\":{\"name\":\"Fieser and Fieser's Reagents for Organic Synthesis\",\"volume\":\"68 1\",\"pages\":\"000-000\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2017-02-21\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"5\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Fieser and Fieser's Reagents for Organic Synthesis\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1002/9780471264194.fos08768.pub2\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Fieser and Fieser's Reagents for Organic Synthesis","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/9780471264194.fos08768.pub2","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 5