{"title":"甲基苯基乙炔的自由基阴离子和阴离子。离子在质子化和电子转移过程中的作用","authors":"G. Levin, M. Szwarc","doi":"10.1039/C29710001029","DOIUrl":null,"url":null,"abstract":"Kinetic and product studies show that electron transfer to methyl(phenyl)acetylene (MPA) gives its dianions (MPA2–,2Na+) which are protonated by MPA yielding PhCHMe,Na+ and PhCCH2,Na+ as the products.","PeriodicalId":17278,"journal":{"name":"Journal of The Chemical Society D: Chemical Communications","volume":"40 1","pages":"1029-1031"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Radical-anions and dianions of methylphenylacetylene. The role of dianions in protonation and electron-transfer processes\",\"authors\":\"G. Levin, M. Szwarc\",\"doi\":\"10.1039/C29710001029\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Kinetic and product studies show that electron transfer to methyl(phenyl)acetylene (MPA) gives its dianions (MPA2–,2Na+) which are protonated by MPA yielding PhCHMe,Na+ and PhCCH2,Na+ as the products.\",\"PeriodicalId\":17278,\"journal\":{\"name\":\"Journal of The Chemical Society D: Chemical Communications\",\"volume\":\"40 1\",\"pages\":\"1029-1031\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society D: Chemical Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/C29710001029\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society D: Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C29710001029","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Radical-anions and dianions of methylphenylacetylene. The role of dianions in protonation and electron-transfer processes
Kinetic and product studies show that electron transfer to methyl(phenyl)acetylene (MPA) gives its dianions (MPA2–,2Na+) which are protonated by MPA yielding PhCHMe,Na+ and PhCCH2,Na+ as the products.
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