环氧氯丙烷交联纤维素基材料的研究进展

Liliane O. Mota, Iara F. Gimenez
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引用次数: 8

摘要

生物聚合物受到几个不同领域研究者的关注。纤维素链上的羟基可以进行化学修饰,以改善其物理化学性质,从而在不同领域得到应用,例如用于植入物的生物材料,从水中去除化学成分以及用于输送药物和肥料的水凝胶。在此背景下,化学交联剂也可以为纤维素基材料及其衍生物带来优势,提高其热稳定性、水凝胶的表面积和膨胀度。在众多的化学交联剂中,环氧氯丙烷近年来被用于制备基于纤维素和其他生物聚合物的材料。因此,在这里,我们的目的是回顾最近报道的纤维素基材料与环氧氯丙烷交联的比较方法与其他常见的试剂,如戊二醛和柠檬酸,它们的优点和缺点以及未来的前景。
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Cellulose-Based Materials Crosslinked with Epichlorohydrin: A Mini Review
biopolymer attention by researchers in several different fields. Hydroxyl groups on cellulose chains can be chemically modified in order to improve physico-chemical properties enabling applications in different areas such as biomaterials for implants, removal of chemical components from water and hydrogels for the delivery of drugs and fertilizers. In this context, chemical crosslinkers may also bring advantages to cellulose-based materials and derivatives improving their thermal stability, surface area and swelling degree of hydrogels. Among many chemical crosslinkers, epichlorohydrin has been used in recent years to prepare materials based on cellulose and other biopolymers. Thus, here we aim to review recent works reporting cellulose-based materials crosslinked with epichlorohydrin in a comparative approach with other common agents such as glutaraldehyde and citric acid, their advantages and disadvantages as well as future prospects.
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