邻苯二甲酸苯并咪唑晶体的合成、结构、光谱、光学和力学研究

S. N., A. B, A. Kumar R, Mathammal R
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引用次数: 3

摘要

采用慢蒸发溶液生长技术,制备了有机非线性邻苯二甲酸苯并咪唑晶体。该晶体属于正交晶系空间群P21。用红外光谱对晶体中的官能团进行了鉴定。紫外可见光谱研究表明,该晶体在截止区域为205 nm处具有优异的透过率。光致发光光谱显示紫色发射。根据发射光谱计算色度坐标,通过色度图表征生长晶体的发射强度。电介质的研究发现了一种将晶体用于光电器件的方法。维氏硬度试验显示了其力学性能。在SHG试验中通过绿色排放验证了NLO的性能。图1:慢蒸发法生长的BPA晶体。引用本文:Sudha N, Abinaya B, Arun Kumar R, Mathammal R (2018) NLO应用的邻苯二甲酸苯并咪唑晶体的合成、结构、光谱、光学和力学研究。[J] .激光光学学报,5(5):184。2469 - 410 - x.1000184 doi: 10.4172 /
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Synthesis, Structural, Spectral, Optical and Mechanical Study of Benzimidazolium Phthalate crystals for NLO Applications
Organic nonlinear crystal benzimidazolium phthalate have been grown by slow evaporation solution growth technique. The crystal belongs to orthorhombic crystal system space group P21. The functional groups present in the crystal were identified by FT-IR spectrum. The UV-Visible spectrum study reveals that the crystal has excellent transmittance the cut-off region being 205 nm. The photoluminescence spectrum shows violet emission. The chromaticity coordinates are calculated from the emission spectra and the emission intensity of the grown crystal is characterized through color chromaticity diagram. Dielectric studies find a way for the crystal to be used for opto electronic devices. Vicker’s hardness test shows its mechanical behavior. The NLO property was confirmed by green emission in SHG test. Figure 1: As grown crystal of BPA by slow evaporation method. Citation: Sudha N, Abinaya B, Arun Kumar R, Mathammal R (2018) Synthesis, Structural, Spectral, Optical and Mechanical Study of Benzimidazolium Phthalate crystals for NLO Applications. J Laser Opt Photonics 5: 184. doi: 10.4172/2469-410X.1000184
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