吡啶配位化合物的光谱和结构

Spectrochimica Acta Pub Date : 1966-08-01 DOI:10.1016/0371-1951(66)80146-7

F. Herbelin, J.D. Herbelin, J.P. Mathieu, H. Poulet

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引用次数: 30

摘要

在100 ~ 3200 cm−1范围内观察到15种吡啶与Pt、Rh、Ir配位化合物的红外吸收光谱;在某些情况下，还观察到紫外线和拉曼光谱。讨论了配位对吡啶振动谱的影响、配位单元的结构以及顺反异构体的谱差异。

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Spectres et structure de composés de coordination pyridines

Infra-red absorption spectra of 15 coordination compounds of pyridine with Pt, Rh and Ir have been observed between 100 and 3200 cm⁻¹; in some cases ultra-violet and Raman spectra have also been observed. The influence of co-ordination on the vibration spectrum of pyridine, the structure of the co-ordinated units and the differences in the spectra of cis-trans isomers are discussed.

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Spectrochimica Acta

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