SnO2:Sb (x = 0.00, 0.03)粉末的红外光谱研究

Ahmad Khoudro, Salama abu alshamlat
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摘要

半导体金属氧化物的纳米晶体以其有趣的性质引起了人们的广泛关注。因此,我们研究了纯氧化锡粉和Sb掺杂氧化锡粉的一些物理性质,通过红外光谱测量,纯氧化锡粉的振动频率为(415.585 - 574.683 - 1641.13 - 2125.3- 3432.67)cm -1,而Sb掺杂氧化锡粉的振动频率为(x=0.03),其中最突出的是(573.719 - 941.092 - 1384.64 - 1637.27 - 3415.56)cm -1;研究表明,在掺杂样品中,吸光度和吸收系数的最大值分别为A = 0.819, α = 18.839 cm -1,对应波数λ = 573.719 cm -1;在纯样品中,光电导率的最大值为0.0831(Ωcm) -1,对应波数λ = 3432.67 cm -1;纯氧化锡的折射率范围为[1.832 ~ 2.371]。Sb掺杂氧化锡粉末的折射率在[1.122 ~ 2.152]之间。
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Studying the Infrared Spectroscopy of the SnO2:Sb (x = 0.00, 0.03) Powders
The nanocrystals of semiconducting metal oxides have attracted great attention because of their interesting properties. Therefore, our study of some physical properties of the pure and Sb doping Tin Oxide powder , The measurement of the infrared spectrum of pure tin oxide powder shows vibrational frequencies (415.585 - 574.683 - 1641.13 – 2125.3- 3432.67) cm -1 and for Sb doping tin oxide ;(x=0.03) shows vibration frequencies and the most prominent is ( 573.719 – 941.092 – 1384.64 – 1637.27 – 3415.56 ) cm -1 , the study showed that the greatest value of the absorbance and absorption coefficient was in doping sample respectively A = 0.819, α = 18.839 cm -1 corresponding to the wavenumber ʋ = 573.719 cm -1 , the greatest value of the optical conductivity was in pure sample 0.0831(Ωcm) -1 corresponding to the wavenumber ʋ = 3432.67 cm -1 and the refractive index for pure tin oxide ranged from [1.832 - 2.371]. As for the Sb doping Tin Oxide powder, the refractive index value was between [1.122 – 2.152 ].
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