CuO-纳米复合材料:合成芳基- 14h -二苯并[a-j]杂蒽的高效可回收催化剂

J. Albadi, Abdolhossein Razeghi, H. Abbaszadeh, Azam Mansournezhad
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引用次数: 14

摘要

CuO-CeO2纳米复合材料是一种高效的可回收催化剂,用于无溶剂条件下合成芳基- 14h -二苯并[a-j]杂蒽。采用共沉淀法合成催化剂,并用x射线粉末衍射(XRD)、BET比表面积、场发射扫描电镜(FESEM)和能谱分析(EDS)对催化剂进行了表征。铜纳米颗粒以细相和非晶相的形式分散在氧化铈表面,形成了平均尺寸约为33 nm的纳米团簇。该催化剂可以通过简单的过滤回收,连续循环8次而不损失任何效率。该方法具有处理简单、反应条件温和、反应时间短、产品收率高等优点。
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CuO- Nanocomposite: An Efficient Recyclable Catalyst for the Synthesis of Aryl-14H-dibenzo[a-j]xanthenes
CuO-CeO2 nanocomposite is reported as a highly efficient recyclable catalyst that is applied for the synthesis of Aryl-14H-dibenzo[a-j]xanthenes under solvent-free conditions. The catalyst was synthesized by coprecipitation method and characterized by X-ray powder diffraction (XRD), BET specific surface area, field emission scanning electron microscopy (FESEM), and energy dispersive spectroscopy (EDS) analysis. The copper nanoparticles are dispersed as fine and amorphous phases on the surface of ceria and made nanoclusters with average size of about 33 nm. This catalyst can be recovered by simple filtration and recycled up to 8 consecutive runs without any losing of its efficiency. This procedure provides several advantages such as simple workup, mild reaction conditions, short reaction times, and high yields of the products.
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