芙蓉提取物抑制铜阳极溶解的潜力

Q2 Materials Science Revista de Chimie Pub Date : 2022-07-29 DOI:10.37358/rc.22.3.8536
F. Abouzeid, Sultanah Alshammery
{"title":"芙蓉提取物抑制铜阳极溶解的潜力","authors":"F. Abouzeid, Sultanah Alshammery","doi":"10.37358/rc.22.3.8536","DOIUrl":null,"url":null,"abstract":"\nCopper electro dissolution in H3PO4 acid is examined in solution containing different concentration of Hibiscus extract (Hibiscuss abdariffa). Potential of anode limiting current relation were computed and estimate of gently raising Hibiscus extract concentration (500-2000 ppm), The results reveal that Hibiscus extraction as a natural product has strong retardation behavior ranging from 24.5 � 42.1 % and the thermodynamic factors, adsorption isotherm and dimensionless parameters were given. Copper dissolution behavior in Hibiscus extract containing solution was investigated below ordinary convection and rotating cylinder electrode (RCE) as a compulsory convection. The rotating cylinder electrode RCE speed was investigated. The limiting current increases with increasing rotation, which indicates that the anodic corrosion is a diffusion-controlled process. The limiting current were reduced with raising extract plant concentration and raise with amplifying temperature from 293 -313 K). The activation energy values established which reaction rate was controlled via diffusion. Hibiscus extract adsorption follow Flory Huggins and kinetic thermodynamic models. The result at several circumstance was commanded via dimensionless correlations Sherwood (Sh), Schmidt (Sc) and Reynolds (Re) numbers.\n","PeriodicalId":21296,"journal":{"name":"Revista de Chimie","volume":"28 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2022-07-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"The Hibiscus extract Potential in Inhibiting Anodic Dissolution of Copper\",\"authors\":\"F. Abouzeid, Sultanah Alshammery\",\"doi\":\"10.37358/rc.22.3.8536\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"\\nCopper electro dissolution in H3PO4 acid is examined in solution containing different concentration of Hibiscus extract (Hibiscuss abdariffa). Potential of anode limiting current relation were computed and estimate of gently raising Hibiscus extract concentration (500-2000 ppm), The results reveal that Hibiscus extraction as a natural product has strong retardation behavior ranging from 24.5 � 42.1 % and the thermodynamic factors, adsorption isotherm and dimensionless parameters were given. Copper dissolution behavior in Hibiscus extract containing solution was investigated below ordinary convection and rotating cylinder electrode (RCE) as a compulsory convection. The rotating cylinder electrode RCE speed was investigated. The limiting current increases with increasing rotation, which indicates that the anodic corrosion is a diffusion-controlled process. The limiting current were reduced with raising extract plant concentration and raise with amplifying temperature from 293 -313 K). The activation energy values established which reaction rate was controlled via diffusion. Hibiscus extract adsorption follow Flory Huggins and kinetic thermodynamic models. The result at several circumstance was commanded via dimensionless correlations Sherwood (Sh), Schmidt (Sc) and Reynolds (Re) numbers.\\n\",\"PeriodicalId\":21296,\"journal\":{\"name\":\"Revista de Chimie\",\"volume\":\"28 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2022-07-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Revista de Chimie\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.37358/rc.22.3.8536\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"Materials Science\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Revista de Chimie","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.37358/rc.22.3.8536","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"Materials Science","Score":null,"Total":0}
引用次数: 0

摘要

研究了含不同浓度芙蓉提取物溶液中铜在H3PO4酸中的电溶性。计算了木槿提取物浓度平缓升高(500 ~ 2000 ppm)的阳极极限电流关系电位,并对其进行了估计。结果表明,木槿提取物作为天然产物具有较强的缓蚀性,缓蚀范围为24.5% ~ 42.1%,并给出了热力学因素、吸附等温线和无因次参数。以普通对流和旋转圆柱电极(RCE)为强制对流,研究了木槿提取物溶液中铜的溶解行为。研究了旋转圆柱电极的RCE速度。极限电流随转速的增加而增大,表明阳极腐蚀是扩散控制的过程。极限电流随萃取物浓度的升高而降低,随放大温度的升高而升高(293 ~ 313 K),确定了通过扩散控制反应速率的活化能值。芙蓉提取物吸附遵循Flory Huggins和动力学热力学模型。在几种情况下的结果是通过无量纲相关性Sherwood (Sh), Schmidt (Sc)和Reynolds (Re)数来控制的。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
The Hibiscus extract Potential in Inhibiting Anodic Dissolution of Copper
Copper electro dissolution in H3PO4 acid is examined in solution containing different concentration of Hibiscus extract (Hibiscuss abdariffa). Potential of anode limiting current relation were computed and estimate of gently raising Hibiscus extract concentration (500-2000 ppm), The results reveal that Hibiscus extraction as a natural product has strong retardation behavior ranging from 24.5 � 42.1 % and the thermodynamic factors, adsorption isotherm and dimensionless parameters were given. Copper dissolution behavior in Hibiscus extract containing solution was investigated below ordinary convection and rotating cylinder electrode (RCE) as a compulsory convection. The rotating cylinder electrode RCE speed was investigated. The limiting current increases with increasing rotation, which indicates that the anodic corrosion is a diffusion-controlled process. The limiting current were reduced with raising extract plant concentration and raise with amplifying temperature from 293 -313 K). The activation energy values established which reaction rate was controlled via diffusion. Hibiscus extract adsorption follow Flory Huggins and kinetic thermodynamic models. The result at several circumstance was commanded via dimensionless correlations Sherwood (Sh), Schmidt (Sc) and Reynolds (Re) numbers.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Revista de Chimie
Revista de Chimie 化学-工程:化工
自引率
0.00%
发文量
54
审稿时长
3-6 weeks
期刊介绍: Revista de Chimie publishes original scientific studies submitted by romanian and foreign researchers and offers worldwide recognition of articles in many countries enabling their review in the publications of other researchers. Published articles are in various fields of research: * Chemistry * Petrochemistry * Chemical engineering * Process equipment * Biotechnology * Environment protection * Marketing & Management * Applications in medicine * Dental medicine * Pharmacy
期刊最新文献
Separation and Identification of Molecular Species by GC-MS for the Reaction Mixture with Methyltrimethoxysilane (MTMOS) Computational Structural Assessment on the Stereochemistry of the Transition Metal Complex Formed by a Naphthalene-1,4-dione Based Ligand with Divalent Nickel Analysis of Octane Retention Prediction Model for Catalytic Cracked Gasoline Based on Ridge Regression Model and Gradient Descent Optimization Separation and Identification of Molecular Species by GC-MS for the Reaction Mixture with Methyltrimethoxysilane (MTMOS) Computational Structural Assessment on the Stereochemistry of the Transition Metal Complex Formed by a Naphthalene-1,4-dione Based Ligand with Divalent Nickel
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1