纳米材料在高温下改善聚合物基砾石充填液

R. Prabhu, J. Santamaría, Nirupama A Vaidya, P. Abivin, V. Lafitte, B. Gadiyar
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摘要

研究人员开发了一种砾石充填液系统,用于290°F以上的高温应用,该系统由黄原胶和高温砾石悬浮液添加剂组成。到目前为止,该流体系统已经成功地在四次裸眼砾石充填作业中进行了泵送,验证了其在包括分流管的Alternate Path砾石充填技术中的适用性。实验室测试表明,该流体具有良好的砾石悬浮性、流变性和破碎剖面,可用于清理,并且在生产过程中损害最小。黄原胶已用于砾石充填应用多年。然而,黄原胶本身在290°F以上的温度下无法悬浮砾石,这可能是由于热激活聚合物降解的开始。本文表明,加入一种新开发的纳米添加剂可以大大提高砾石的悬浮能力。这种添加剂是一种特殊设计的多功能纳米材料,在过去的粘弹性表面活性剂流体中具有良好的记录。在本研究中,我们成功地将这种添加剂应用于聚合物基载体流体,如黄原胶,有效地将其应用范围提高到325°F。加入这种悬浮添加剂后,流体体系中的黄原胶浓度也可以降低,这还有其他潜在的好处,比如在凝胶破裂后更好地清理。在作业之前,对流体进行了广泛的实验室评估。高压/高温(HP/HT)流变学测量使用行业标准流变仪在不同剪切速率下进行,以满足分流管应用的特定粘度要求。在要求的井底静态温度下,将特殊的加压槽浸入油浴中进行砾石悬浮测试,结果表明纳米添加剂改善了砾石悬浮。通过粘度测量,还验证了常规氧化破胶剂对流体的破胶效果。地层响应测试表明,流体清除效果非常好,渗透率恢复了90%。实验室测试和成功的现场应用证明了这种新型流体体系的有效性。
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Nanomaterials Improve Polymer-Based Gravel-Packing Fluids at High Temperature
A gravel packing fluid system was developed for elevated temperature applications above 290°F comprised of xanthan gum and a high-temperature gravel suspension additive. This fluid system has been successfully pumped in four openhole gravel packing operations so far, validating its suitability for Alternate Path gravel packing technology involving shunt tubes. Laboratory qualification testing for this fluid showed excellent gravel suspension, rheology, and breaking profiles for cleanup and minimal damage during production. Xanthan gels have been used in gravel packing applications for many years. However, by itself, xanthan was unable to suspend gravel at temperatures above 290°F possibly due to onset of thermally activated polymer degradation. This paper demonstrates that gravel suspension ability can be vastly improved with the addition of a recently developed nano-additive. This additive is a specially designed versatile nanosized material that has a proven track record with visco-elastic surfactant fluids in the past. In the present study, we show the successful application of this additive with polymer-based carrier fluids such as xanthan, effectively increasing their application range to 325°F. With the inclusion of this suspension additive, xanthan concentration in the fluid system can also be reduced, which has other potential benefits such as better cleanup after gel break. Extensive laboratory evaluation for fluid qualification was performed prior to the job. High-pressure/high-temperature (HP/HT) rheology measurements were performed using industry-standard rheometers at various shear rates to match specific viscosity requirements for shunt tube applications. Gravel suspension tests performed using special pressurized cells immersed in oil bath at the required bottomhole static temperature showed improved gravel suspension with the nano-additive. Fluid breaking with conventional oxidative breaker was also demonstrated with viscosity measurements. Formation response tests showed very good fluid cleanup with 90% regained permeability. Laboratory testing and successful field applications have proven the effectiveness of this new fluid system.
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