原油和石油产品的水溶性

Wan Ying Shiu , Mark Bobra , Alice M. Bobra , Aila Maijanen , Leena Suntio , Donald Mackay
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引用次数: 82

摘要

报道了42种原油和石油产品在水中的溶解度与温度、盐度、石油风化和水油体积比的关系。讨论了几种分析技术(吹扫捕集气相色谱法、高压液相色谱法和荧光法)测定溶解烃浓度的适用性。详细讨论了油水体积比对油类在水中表观溶解度的影响。
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The water solubility of crude oils and petroleum products

Solubilities are reported for 42 crude oil and petroleum products in water as a function of temperature, salinity, oil weathering and water-to-oil volume ratio. The applicability of several analytical techniques (purge-and-trap gas chromatography, high pressure liquid chromatography, and fluorescence) for the determination of dissolved hydrocarbon concentrations is discussed critically. The effect of water-to-oil volume ratio on the apparent solubility of oils in water is discussed in detail.

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