Z. Yildiz, Hacer Aysen Onen, A. Gungor, Youjiang Wang, K. Jacob
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引用次数: 8
摘要
摘要通过改变NCO:OH的比例合成了一系列可双固化的聚氨酯甲基丙烯酸酯基低聚物，并以三甲基丙烯酸三甲基丙烷和三环癸烷二甲醇二丙烯酸酯(TCDDA)为反应稀释剂加入胶粘剂配方中。研究了NCO:OH比和反应稀释剂类型对紫外光固化自由膜结构性能和聚酯帘子/橡胶表面粘附性能的影响。当NCO:OH比为4时，以TCDDA作为反应稀释剂，得到了103 N cm−1的最高粘附强度。图形抽象
Effects of NCO/OH Ratio and Reactive Diluent Type on the Adhesion Strength of Polyurethane Methacrylates for Cord/Rubber Composites
ABSTRACT A series of dual curable polyurethane methacrylate-based oligomers were synthesized by changing the NCO:OH ratio and then were included in adhesive formulations using trimethylolpropane trimethacrylate and tricyclodecane dimethanol diacrylate (TCDDA) as reactive diluents. The effects of NCO:OH ratio and reactive diluent type on the structural properties of UV-cured free films and adhesion properties between polyester cord/rubber surfaces were studied. The highest adhesion strength of the 103 N cm−1 was obtained when the NCO:OH ratio was set as 4 and the TCDDA was used as a reactive diluent. GRAPHICAL ABSTRACT
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