铁氧体(Fe3O4)基聚合物纳米复合材料的研究进展与挑战

O. P. Bajpai, D. Setua, S. Chattopadhyay
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引用次数: 17

摘要

本文主要对铁氧体及其聚合物基纳米复合材料进行了研究。铁氧体颗粒在生物技术、磁共振成像(MRI)和数据存储等领域有着广泛的应用,已成为一种重要的研究材料。铁素体fe3o4颗粒在粒径小于10 ~ 30 nm时表现出最佳性能。这种情况的发生是由于这种粒子的超顺磁性。在超顺磁范围内,这些粒子表现出零剩余力或矫顽力。因此,铁氧体纳米颗粒及其聚合物纳米复合材料的各种性能在很大程度上取决于颗粒在聚合物基体中的大小和分布。此外,还观察到纳米晶体的形状在决定其基本性质方面起着重要作用。这些粒子在较长时间内表现出不稳定性,这是由于高表面能产生的团块的形成。因此,已经开发出诸如接枝和二氧化硅/碳或聚合物涂层等保护策略来化学地稳定它们。目前,硅基化技术主要用于纳米颗粒的修饰。实验发现,由聚合物基体和铁氧体组成的纳米复合材料在刚度、断裂韧性、感应能力(磁和电)、冲击能吸收和对生物物种的电催化活性等方面都有显著改善。
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A Brief Overview on Ferrite (Fe3O4) Based Polymeric Nanocomposites: Recent Developments and Challenges
In this article, we have mainly discussed about ferrite (Fe 3 O 4 ) and its polymer based nanocomposites. Ferrite particles have become an important research material because of their vast applications in the field of biotechnology, magnetic resonance imaging (MRI), and data storage. It has been observed that ferrite Fe 3 O 4 particles show best performance for size less than 10-30 nm. This happens due to the super paramagnetic nature of such particles. In super paramagnetic range these particles exhibit zero remanence or coercivity. Therefore, various properties of ferrite (Fe 3 O 4 ) nanoparticles and its polymer nanocomposites are very much dependent on the size, and distribution of the particles in the polymeric matrix. Moreover, it has been also observed that the shape of the nanocrystals plays important role in the determination of their fundamental properties. These particles show instability over longer times due to the formation of agglomerates generated by high surface energies. Therefore, protection strategies such as grafting and coatings with silica/carbon or polymers have been developed to stabilize them chemically. Recently, silylation technique is mainly used for the modification of nanoparticles. Experimentally, it has been observed that nanocomposites composed of polymer matrices and ferrite showed substantial improvements in stiffness, fracture toughness, sensing ability (magnetic as well as electric), impact energy absorption, and electro-catalytic activities to bio-species.
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