铝渣衍生层状双氢氧化物在去除水溶液中有机化合物中的应用

N. Murayama, T. Miyoshi, Takumi Hayashi, J. Shibata
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引用次数: 1

摘要

如表面活性剂,螯合剂等。例如,各种阴离子表面活性剂,如十二烷基硫酸盐离子、十二烷基苯磺酸盐离子和辛烷磺酸盐离子,很容易通过阴离子交换反应捕获在LDH结构中。摘要以铝渣为原料,通过表面活性剂改性制备了具有疏水表面的层状双氢氧化物(LDHs),探索了铝渣回收利用的新方法。研究了以十二烷基硫酸盐离子(DS -)为表面活性剂改性的LDHs的晶体结构、表面织构和接触角等物理性能。采用DS型LDHs (DS - LDHs)对水溶液中的稀甲苯进行了脱除试验。通过与DS -进行阴离子交换,可以成功地对铝渣合成的低分子量氢氧化钠进行有机改性。水溶液中甲苯(初始浓度;使用DS - LDHs去除10和50 mg/dm(3)。结果表明,以铝渣为原料合成的DS - LDHs可作为水溶液中稀有机化合物的优良吸附剂。
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Application of Aluminum Dross-Derived Layered Double Hydroxides to Removal of Organic Compounds in Aqueous Solution
like surfactant, chelating agent and so on 16,17 . For exam-ple, various anionic surfactants such as dodecyl sulfate ions, dodecylbenzene sulfonate ions and octane sulfonate ions are easily captured in the LDH structure by an anion exchange reaction. Abstract Layered double hydroxides (LDHs) with hydrophobic surface by surfactant modification were prepared using aluminum dross as a raw material, to develop a new recycling method of aluminum dross. The physical properties including crystal structure, surface texture and contact angle were investigated for the LDHs modified with dodecyl sulfate ions (DS – ) as a surfactant. The removal tests of dilute toluene in aqueous solution were demonstrated using the DS – type LDHs (DS – LDHs). Organic modification of the LDHs synthesized from aluminum dross can be achieved success-fully by an anion exchange with DS – . The toluene in aqueous solution (initial concentration; 10 and 50 mg/dm 3 ) is removed using the DS – LDHs. It was clarified that the DS – LDHs synthesized from aluminum dross can be used as an excellent adsorbent for dilute organic compounds in aqueous solution.
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