应用数学模型预测北马其顿斯特鲁加市饮用水中三卤甲烷的含量

Bujar H. Durmishi, Arbana Durmishi, Pajtim S. Bytici, Arianit A. Reka, A. Shabani
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摘要

三卤甲烷(THMs)是氯与饮用水中的有机物反应产生的主要消毒副产物。高浓度的thm是有害的,对肝脏、胰腺、神经系统和发育器官具有致癌作用,而对女性则可能导致流产。因此,THMs最近受到了科学界和公众的高度关注。因此,必须不断监测thm。THMs主要通过气相色谱法测定,该方法难度大,成本高。为了避免这种情况,在过去几年中,使用数学模型来预测饮用水中的THMs。通过快速测量一些简单的饮用水水质参数的值,并将其代入数学模型中,可以预测饮用水中THMs的含量。本文的目的是预测斯特鲁加市2021年春季饮用水中4个采样点S1、S2、S3和S4的THMs含量。测量参数及其平均值(标准差)分别为:水温(13.56±1.17ºC)、余氯(0.200.00 mg/L)、pH(7.580.03)、电导率(250.899.37µS/cm)、化学需氧量(1.530.06 mg/L)、总溶解固溶体(407.672.89 mg/L)和氯化物(5.260.32 mg/L)。然后将这些值放入数学模型中,通过计算预测饮用水中THMs的含量。采用10个数学模型进行预测,THMs平均值为27.40±10.67µg/L,标准差为27.40±10.67µg/L。从结果可以得出结论,所使用的THMs预测模型取得了成功,该THMs含量不会对公众健康构成风险。
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Application of Mathematical Models for Predicting the Trihalomethanes Content in Drinking Water in the City of Struga, North Macedonia
: Trihalomethanes (THMs) are the main disinfection byproducts created when chlorine reacts with organic matter of the drinking water. THMs in high concentrations are harmful and can be carcinogenic for the liver, pancreas, nervous system, development organs, whereas in women can cause miscarriage. Therefore, THMs recently have concerned very much the scientific community and the general public. Consequently, THMs must be constantly monitored. THMs mainly are determined by the gas chromatography method, which is a difficult procedure and very costly. To avoid this, in the past years the use of mathematical models for prediction of THMs in drinking water is practiced. By fast measuring of the values of some simple parameters of drinking water quality and replacing them in the mathematical models we can predict the THMs content. The aim of this article was the prediction of the THMs content in drinking water in the city of Struga for the spring of 2021 in four sampling points S1, S2, S3 and S4. The measured parameters and their average values with standard deviation were: water temperature (13.56± 1.17 ºC), residual chlorine (0.20  0.00 mg/L), pH (7.58  0.03), electrical conductivity (250.89  9.37 µS/cm), chemical oxygen demand (1.53  0.06 mg/L), total dissolved solids, (407.67  2.89 mg/L) and chlorides (5.26  0.32 mg/L), respectively. These values are then placed in mathematical models and with calculation is predicted the THMs content in drinking water. For prediction were used ten mathematical models and the average value of the THMs with standard deviation was 27.40 ± 10.67 µg/L). From the results we can conclude that the used models for THMs prediction have resulted successful and this content of THMs pose no risk to public health.
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