通过新技术解决石蜡沉积挑战

Saugata Gon, Christopher Russell, Kasper K.J. Baack, Heather Blackwood, A. Hase
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摘要

石蜡沉积是全球生产设施面临的共同挑战,因为生产流体/工艺表面温度会下降,并低于油的蜡样温度(WAT)。虽然化学处理被广泛用于适当地减少蜡沉积,但传统的测试方法,如冷手指,往往无法为该领域推荐合适的产品。目前的研究将提出两种新技术的发展PARA-Window和动态石蜡沉积细胞(DPDC)来解决这些限制。大块油与冷表面之间的温度梯度大已被确定为冷指的主要限制。为了解决这个问题,PARA-Window已经被开发出来,使用近红外光学探头在更现实的温度梯度(5°C)下捕获石蜡沉积。缺少卤水和缺乏剪切已被确定为冷指技术的另一个限制。DPDC用于研究卤水存在下的石蜡沉积和化学有效性。特殊设计的细胞水平放置在摇床浴中,以实现DPDC应用中油和水之间的良好混合。Russell等人(2019)先前的一项研究表明,PARA-Window在WAT周围窄温度梯度下捕获高分子量石蜡链沉积现象的有效性,这些现象与现场沉积非常相似。在这种条件下,传统的测试方法无法捕获大多数油中有意义的产品差异,因此只能推荐晶体改性类型的石蜡化学物质。PARA-Window技术可以将产品选择扩展到其他类型的石蜡化学物质(石蜡晶体改性剂、分散剂和溶剂),如Russell等人(2021)所示。DPDC的使用使我们能够在类似于生产管道系统的条件下,在测试单元内创建油和水的动态混合条件。这使得DPDC可以评估水对石蜡化学(晶体改性剂和分散剂)的影响。本研究介绍了这两种新技术的应用,以筛选不同类型的石蜡化学物质在选定油中的性能,以及它们比冷手指的优势。结果表明,使用这些新技术模拟现场条件可以获得对石蜡产品的新见解。
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Addressing Paraffin Deposition Challenges Through New Technologies
Paraffin deposition is a common challenge for production facilities globally where production fluid/process surface temperature cools down and reach below the wax appearance temperature (WAT) of the oil. Although chemical treatment is used widely for suitable mitigation of wax deposition, conventional test methods like cold finger often fail to recommend the right product for the field. The current study will present development of two new technologies PARA-Window and Dynamic Paraffin Deposition Cell (DPDC)to address such limitations. Large temperature gradient between bulk oil and cold surface has been identified as a major limitation of cold finger. To address this, PARA-Window has been developed to capture the paraffin deposition at a more realistic temperature gradient (5°C) between the bulk oil and surface temperature using a NIR optical probe. Absence of brine and lack of shear has been identified as another limitation of cold finger technique. DPDC has been developed to study paraffin deposition and chemical effectiveness in presence of brine. Specially designed cells are placed horizontally inside a shaker bath to achieve good mixing between oil and water for DPDC application. A prior study by Russell et al., (2019) showed the effectiveness of PARA-Window in capturing deposition phenomena of higher molecular weight paraffin chains that resemble closely to field deposits under narrow temperature gradient around WAT. Conventional test methods fail to capture meaningful product differentiation in most oils under such conditions and hence can only recommend a crystal modifier type of paraffin chemistries. PARA-Window technique can expand product selection to other type of paraffin chemistries (paraffin crystal modifiers, dispersants and solvents) as shown earlier by Russell et al., (2021). The usage of DPDC allows us to create a dynamic mixing condition inside the test cells with both oil and water under a condition similar to production pipe systems. This allows DPDC to assess water effect on paraffin chemistries (crystal modifiers and dispersants). This study presents the usage of these two new technologies to screen performance of different types of paraffin chemistries on select oils and their advantages over cold finger. The results identify how mimicking field conditions using these new technologies can capture new insights into paraffin products.
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