改性硼砂提金的替代方法

IF 1 4区 工程技术 Q4 CHEMISTRY, MULTIDISCIPLINARY Iranian Journal of Chemistry & Chemical Engineering-international English Edition Pub Date : 2021-09-26 DOI:10.30492/IJCCE.2021.138007.4382
I. A. Joseph, E. Eterigho, J. Okafor, C. Are
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引用次数: 0

摘要

在世界许多地方,黄金的开采是由当地的手工矿工进行的,他们使用汞进行开采,汞被认为是一种对人类和生物物理环境非常危险的化学物质。本研究调查了在从矿石中提取黄金时使用硼砂代替汞的情况。研究所用的样品采集于尼日尔州Chanchaga矿区。在600℃的温度下对硫化矿石进行煅烧,以氧化矿石中的硫含量。在提取过程中使用改性硼砂作为金属助熔剂,并使用design Expert 7.0软件通过Box-Behnken实验设计方法对其进行优化。在800 ~ 1000℃、0.8 ~ 3.5℃和15 ~ 30 min的条件下,研究了温度、重矿物精矿与硼砂摩尔比和时间的影响。对样品进行筛分、x射线荧光(XRF)和克拉数分析。在900℃、30 min、重矿精矿与改性硼砂摩尔比为0.8的条件下,金萃取物得率为70.2%。筛分分析表明,提取金在0.3 ~ 0.15 mm范围内实现了明显的解离,x射线荧光显示提取金纯度为88.7%,为22克拉。这种方法可以替代目前使用汞提取黄金的有毒方法。
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Alternative Approach of Gold Extraction using Modified Borax
The extraction of gold in many part of the world is left in the hands of artisanal local miners who do this with the use of mercury which is considered to be a very hazardous chemical to human and the biophysical environment. This research investigated the use of borax as a replacement for mercury in extraction of gold from its ore. The sample used for the study was collected from Chanchaga mining site in Niger State. Calcination of the sulphide ore was done at a temperature of 600 oC in order to oxidize the sulphur content of the ore. The Borax in its modified form was used as a metal flux in the extraction process and this was optimized through Box-Behnken experimental design method using Design Expert 7.0 software. The effect of temperature, mole ratio of heavy mineral concentrate to borax, and time were studied at 800 – 1000 oC, 0.8 – 3.5 and 15-30 min respectively. Sieve, X-Ray Fluorescence (XRF), and carat analysis of the samples were carried out. The percentage yield of gold extract was 70.2 % at 900 oC, 30 min and 0.8 mole ratio of heavy mineral concentrate to modified borax. The sieve analysis shows that visible gold liberation was achieved between 0.3 and 0.15 mm, the X-Ray Fluorescence showed 88.7 % extract gold purity with 22 carat. This method can be a replacement for the current toxic method of gold extraction using mercury.
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来源期刊
CiteScore
2.80
自引率
22.20%
发文量
0
审稿时长
6-12 weeks
期刊介绍: The aim of the Iranian Journal of Chemistry and Chemical Engineering is to foster the growth of educational, scientific and Industrial Research activities among chemists and chemical engineers and to provide a medium for mutual communication and relations between Iranian academia and the industry on the one hand, and the world the scientific community on the other.
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