高强度氟塑料复合材料,在载荷下抗变形能力增强

P. N. Petrova, M. Markova, A. Fedorov
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摘要

介绍了基于聚四氟乙烯(PTFE)和UVIS-AK-P品牌碳纤维的聚合物毛坯塑性变形技术开发的研究成果,以提高其强度和抗蠕变性能。研究了所获得的复合材料的物理力学和摩擦技术特性的依赖性,并与使用先前开发的技术获得的相同成分的复合材料进行了比较。研究表明,利用塑性变形技术提高基于PTFE和UVIS-AK-P碳纤维的PCM的性能是获得高强度、耐磨复合材料的有效解决方案,其特点是增加抗拉伸载荷的能力。所研制的塑性变形复合材料的抗拉强度比原PTFE标准工艺提高3倍,蠕变降低22 ~ 29倍。聚合物毛坯塑性变形技术的结构研究表明,该技术使碳纤维的取向与材料的流动方向一致,使大分子的螺旋构象发生变化,向更稳定的构象过渡,有利于碳纤维的使用性能。这种方法的使用将使获得具有更高抗变形能力的高强度聚合物材料成为可能,有望用于具有高拉伸载荷的加载方案。
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High-strength fluoroplastic composites with increased resistance to deformation under load
This paper presents the results of research on the development of technology for plastic deformation of polymer blanks based on polytetrafluoroethylene (PTFE) and carbon fibers of the UVIS-AK-P brand in order to increase their strength and creep resistance. The dependence of the physico-mechanical and tribotechnical characteristics of the obtained composites is investigated and compared with a composite of the same composition, but obtained using a previously developed technology. It is established that the use of plastic deformation technology for the properties of PCM based on PTFE and carbon fibers of the brand UVIS-AK-P is an effective solution for obtaining high-strength, wear-resistant composites, characterized by increased resistance to tensile loads. The developed composites obtained using plastic deformation are characterized by 3 times increased tensile strength and 22 – 29 times reduced creep compared to the original PTFE obtained by standard technology. Structural studies of the technology of plastic deformation of polymer blanks have shown that this technology leads to the orientation of the carbon fiber (CF) in the direction of the flow of the material and a change in the spiral conformation of macromolecules with a transition to a more stable conformation, which favorably affects its operational properties. The use of this method will make it possible to obtain high-strength polymer materials with increased resistance to deformation, promising for use for loading schemes with high tensile loads.
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