{"title":"金属卟啉配合物薄膜的组成和结构","authors":"Nikolay M. Romanov, Irina B. Zakharova","doi":"10.1016/j.spjpm.2016.05.001","DOIUrl":null,"url":null,"abstract":"<div><p>Thin films based on CuTPP, ZnTPP and FeClTPP (ТРР – TetraPhenylPorphyrin) complexes and manufactured by vacuum deposition under quasi-equilibrium conditions have been investigated. The hot-wall epitaxy method was chosen for the preparation of samples. The structure of objects and their composition were examined by scanning electron microscopy (SEM) and energy dispersive microanalysis (EDX). The CuTPP film was established to form whiskers about 20<!--> <!-->nm in diameter and 5<!--> <!-->µm in length. The structural features and morphology of ZnTPP and FeClTPP films’ surface were revealed. The theoretical interpretation of obtained results was proposed that made it possible to relate the film structure with its composition.</p></div>","PeriodicalId":41808,"journal":{"name":"St Petersburg Polytechnic University Journal-Physics and Mathematics","volume":null,"pages":null},"PeriodicalIF":0.2000,"publicationDate":"2016-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.spjpm.2016.05.001","citationCount":"3","resultStr":"{\"title\":\"The composition and the structure of thin films based on metal porphyrin complexes\",\"authors\":\"Nikolay M. Romanov, Irina B. Zakharova\",\"doi\":\"10.1016/j.spjpm.2016.05.001\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Thin films based on CuTPP, ZnTPP and FeClTPP (ТРР – TetraPhenylPorphyrin) complexes and manufactured by vacuum deposition under quasi-equilibrium conditions have been investigated. The hot-wall epitaxy method was chosen for the preparation of samples. The structure of objects and their composition were examined by scanning electron microscopy (SEM) and energy dispersive microanalysis (EDX). The CuTPP film was established to form whiskers about 20<!--> <!-->nm in diameter and 5<!--> <!-->µm in length. The structural features and morphology of ZnTPP and FeClTPP films’ surface were revealed. The theoretical interpretation of obtained results was proposed that made it possible to relate the film structure with its composition.</p></div>\",\"PeriodicalId\":41808,\"journal\":{\"name\":\"St Petersburg Polytechnic University Journal-Physics and Mathematics\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.2000,\"publicationDate\":\"2016-06-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/j.spjpm.2016.05.001\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"St Petersburg Polytechnic University Journal-Physics and Mathematics\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2405722316300573\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"PHYSICS, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"St Petersburg Polytechnic University Journal-Physics and Mathematics","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2405722316300573","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"PHYSICS, MULTIDISCIPLINARY","Score":null,"Total":0}
The composition and the structure of thin films based on metal porphyrin complexes
Thin films based on CuTPP, ZnTPP and FeClTPP (ТРР – TetraPhenylPorphyrin) complexes and manufactured by vacuum deposition under quasi-equilibrium conditions have been investigated. The hot-wall epitaxy method was chosen for the preparation of samples. The structure of objects and their composition were examined by scanning electron microscopy (SEM) and energy dispersive microanalysis (EDX). The CuTPP film was established to form whiskers about 20 nm in diameter and 5 µm in length. The structural features and morphology of ZnTPP and FeClTPP films’ surface were revealed. The theoretical interpretation of obtained results was proposed that made it possible to relate the film structure with its composition.
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