硬阳极氧化6061-T6铝合金的特性及耐蚀性

S. H. Mohitfar, M. Etminanfar, S. Mahdavi, J. Khalil-Allafi
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摘要

摘要:采用直流电在6061-T6铝合金表面形成硬质阳极镀层。研究了涂层的表面形貌、截面、硬度和腐蚀性能。结果表明,将外加电流密度从55 mA cm−2降低到35 mA cm−2,镀层更均匀,表面缺陷更少,孔隙率更低,硬度值更高。最佳的电解液浓度和硬阳极氧化时间分别为180 g L−1和50 min,从而减少了涂层的缺陷。最佳腐蚀膜的硬度在500 HV左右,腐蚀电流密度为3.2 × 10−9A cm−2。在不同电流密度(30-55 mA cm−2)、时间(40-100 min)和电解质浓度(25-220 g L−1)下制备的所有其他样品的硬度和耐腐蚀性都低于最佳涂层。该涂层的抗极化性能约为裸基材的1100倍。
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Characteristics and corrosion resistance of hard-anodised 6061-T6 aluminium alloy
ABSTRACT Hard anodic coatings were formed on 6061-T6 aluminium alloy samples using direct current. Surface morphology and cross-section of coatings, as well as their hardness and corrosion behaviour, were studied. It was found that decreasing the applied current density from 55 to 35 mA cm−2 resulted in more uniform coatings with fewer surface defects, lower porosity, and higher hardness values. The optimum electrolyte concentration and hard-anodising time, where less defective coatings were achieved, were found to be 180 g L−1 and 50 min, respectively. The hardness of the optimum film was around 500 HV, and its corrosion current density was 3.2 × 10−9A cm−2. All other samples that were produced at different current densities (30-55 mA cm−2), times (40-100 min), and electrolyte concentrations (25-220 g L−1) had lower hardness and corrosion resistance than the optimum coating. The polarisation resistance of the optimum coating was about 1100 times higher than the bare substrate.
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