{"title":"探索性开环聚合。2-乙烯基环砜开环聚合研究","authors":"Iwhan Cho, Sang-Keun Kim, Myong-Hoon Lee","doi":"10.1002/polc.5070740119","DOIUrl":null,"url":null,"abstract":"<p>2-Vinyllhiolane-1,1-dioxide (Ia) and 2-vinylthiane-1,1-dioxide(Ib) have been prepared and polymerized with free radical initiators to obtain poly(sulfonyl-hex-2-enylene) (IIa) and poly(sulfonyl-hept-2-enyIene-<i>co</i>-2-vinylthiane-1,1-dioxide) (IIb), respectively, via a ring-opening mechanism. Structures of the polymers are supported by infrared and <sup>1</sup>H-NMR spectroscopy. Poly(sulfonyl-hex-2-enylene) was insoluble in ordinary organic solvents, but soluble in concentrated sulfuric acid or trifluoroacetic acid, and was white amorphous powder, softening at 168°C. Degradation occurred at 294°C under N<sub>2</sub>. Ia copolymerized with certain vinyl monomers, such as ethyl acrylate, but its copolymerization behavior was different from those of normal vinyl monomers.</p>","PeriodicalId":16867,"journal":{"name":"Journal of Polymer Science: Polymer Symposia","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1986-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1002/polc.5070740119","citationCount":"12","resultStr":"{\"title\":\"Exploratory ring-opening polymerization. XIIL† ring-opening polymerization of 2-vinyl cyclic sulfones‡\",\"authors\":\"Iwhan Cho, Sang-Keun Kim, Myong-Hoon Lee\",\"doi\":\"10.1002/polc.5070740119\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>2-Vinyllhiolane-1,1-dioxide (Ia) and 2-vinylthiane-1,1-dioxide(Ib) have been prepared and polymerized with free radical initiators to obtain poly(sulfonyl-hex-2-enylene) (IIa) and poly(sulfonyl-hept-2-enyIene-<i>co</i>-2-vinylthiane-1,1-dioxide) (IIb), respectively, via a ring-opening mechanism. Structures of the polymers are supported by infrared and <sup>1</sup>H-NMR spectroscopy. Poly(sulfonyl-hex-2-enylene) was insoluble in ordinary organic solvents, but soluble in concentrated sulfuric acid or trifluoroacetic acid, and was white amorphous powder, softening at 168°C. Degradation occurred at 294°C under N<sub>2</sub>. Ia copolymerized with certain vinyl monomers, such as ethyl acrylate, but its copolymerization behavior was different from those of normal vinyl monomers.</p>\",\"PeriodicalId\":16867,\"journal\":{\"name\":\"Journal of Polymer Science: Polymer Symposia\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1986-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1002/polc.5070740119\",\"citationCount\":\"12\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Polymer Science: Polymer Symposia\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/polc.5070740119\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Polymer Science: Polymer Symposia","FirstCategoryId":"1085","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/polc.5070740119","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Exploratory ring-opening polymerization. XIIL† ring-opening polymerization of 2-vinyl cyclic sulfones‡
2-Vinyllhiolane-1,1-dioxide (Ia) and 2-vinylthiane-1,1-dioxide(Ib) have been prepared and polymerized with free radical initiators to obtain poly(sulfonyl-hex-2-enylene) (IIa) and poly(sulfonyl-hept-2-enyIene-co-2-vinylthiane-1,1-dioxide) (IIb), respectively, via a ring-opening mechanism. Structures of the polymers are supported by infrared and 1H-NMR spectroscopy. Poly(sulfonyl-hex-2-enylene) was insoluble in ordinary organic solvents, but soluble in concentrated sulfuric acid or trifluoroacetic acid, and was white amorphous powder, softening at 168°C. Degradation occurred at 294°C under N2. Ia copolymerized with certain vinyl monomers, such as ethyl acrylate, but its copolymerization behavior was different from those of normal vinyl monomers.
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