磷酸盐处理对杨木纤维/高密度聚乙烯复合材料界面性能的影响

Liang Caiping
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摘要

以磷酸酯溶液为改性剂对杨木纤维进行处理,然后与高密度聚乙烯熔融共混制备木纤维/高密度聚乙烯可降解复合材料。研究了磷酸盐溶液浓度对复合材料抗拉强度和抗折强度的影响。用扫描电镜观察了经磷酸盐处理的杨树纤维的表面形貌。结果表明,磷酸盐处理提高了杨木纤维的表面粗糙度,提高了单根纤维的强度,有效地提高了与HDPE基体的机械附着力。然而,当磷酸盐浓度过大时,纤维素分子链的密度降低,整个纤维的力学性能降低。当磷酸盐溶液浓度为3%,处理时间为4 h,处理温度为60℃时,杨木纤维/HDPE复合材料的拉伸性能、弯曲性能和耐水性最佳。
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Effect of phosphate treatment on interfacial properties of poplar fiber/high-density polyethylene composites
Poplar fiber was treated with phosphate solution as a modifier and then wood fiber/high-density polyethylene (HDPE) degradable composite was prepared by melt blending with HDPE. The effects of phosphate solution concentration on tensile strength and flexural strength of composites were investigated. The surface morphology of phosphate-treated poplar fibers was observed by scanning electron microscopy. The results show that the phosphate treatment increases the surface roughness of the poplar fiber, increases the strength of the single fiber, and effectively improves the mechanical adhesion to the HDPE matrix. However, when the phosphate concentration is too large, the density of the cellulose molecular chains is lowered, and the mechanical properties of the whole fiber are lowered. When the concentration of phosphate solution is 3%, the treatment time is 4 h, and the treatment temperature is 60°C, the tensile properties, bending properties, and water resistance of poplar fiber/HDPE composites are the best.
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