高温浸水环境下UPE涂胶地下管道用GFRP开裂及热降解研究

IF 0.4 Q4 ENGINEERING, GEOLOGICAL Journal of the Korean Geosynthetic Society Pub Date : 2018-01-01 DOI:10.12814/JKGSS.2018.17.4.169
Daehoon Kim, J. Eom, Youngjong Ko, Lee, Kang-il
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引用次数: 1

摘要

玻璃纤维增强聚酯(GFRP)复合材料广泛应用于地下管道、储罐、船体等要求长期耐水的恶劣环境中作为结构材料。特别是当这些材料浸入水中时,由于凝胶涂层和复合材料之间通过渗透过程发生分层,可能会损坏这些材料。为了提高地下管道用复合材料的耐久性,本研究采用真空灌注工艺对UPE(不饱和聚酯)胶衣进行表面处理,制备GFRP复合材料。对涂有凝胶涂层的复合材料表面在水浸环境(60°C、75°C和85°C)下的表面缺陷、开裂和硬度变化特征进行了检测。根据水浸温度,利用微CT成像技术研究了裂纹的穿透深度。结果表明,复合材料在75℃和85℃时出现裂纹,导致材料的耐久性损失。初始裂纹开始点定义为失效时间,使用Arrhenius方程测量23°C时的预期寿命。该研究结果有望应用于土木、建筑、海洋等各种应用胶衣的工业领域的可靠性评估。
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Study on the Crack and Thermal Degradation of GFRP for UPE Gelcoat Coated Underground Pipes Under the High Temperature Water-Immersion Environment
Glass fiber reinforced polyester (GFRP) composites are widely used as structural materials in harsh environment such as underground pipes, tanks and boat hulls, which requires long-term water resistance. Especially, these materials might be damaged due to delamination between gelcoat and composites through an osmotic process when they are immersed in water. In this study, GFRP laminates were prepared by surface treatment of UPE (unsaturated polyester) gelcoat by vacuum infusion process to improve the durability of composite materials used in underground pipes. The composite surface coated with gelcoat was examined for surface defects, cracking, and hardness change characteristics in water-immersion environments (different temperatures of 60°C, 75°C, and 85°C). The penetration depth of cracks was investigated by micro CT imaging according to water immersion temperature. It was confirmed that cracks developed into the composites material at 75°C and 85°C causing loss of durability of the materials. The point at which the initial crack initiated was defined as the failure time and the life expectancy at 23°C was measured using the Arrhenius equation. The results from this study is expected to be applied to reliability evaluation of various industrial fields where gelcoat is applied such as civil engineering, construction, and marine industry.
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