ZnO-CeO2-TiO2复合材料的制备及其催化性能

Xiu-ping Li, Rongxiang Zhao, Heng Jiang, Y. Zhai, Pei-hua Ma
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引用次数: 10

摘要

以抗坏血酸为助燃剂,采用燃烧法快速合成了ZnO-CeO2-TiO2复合氧化物。采用XRD、FI-IR、UV-Vis、BET和SEM对合成的样品进行了表征。通过改变燃烧剂、锌、钛、铈离子的摩尔比,优化了ZnO-CeO2-TiO2复合氧化物的形貌和紫外吸收性能。当燃烧剂、锌离子、钛离子、铈离子的摩尔比为8:4:0.25:1时,复合氧化物具有较强的紫外吸收和光催化性能。其原因可以归结为ZnO、TiO2与CeO2共同对亚甲基蓝进行了降解和脱色。当燃烧剂与锌、钛、铈离子的摩尔比为8:1:0.25:1时,复合氧化物的脱色效果较好。其原因是复合材料的XRD图峰与CeO2完全相同,但复合材料的结晶度更好,因此复合材料的性能优于CeO2。
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Preparation and Catalytic Properties of ZnO-CeO2-TiO2 Composite
ZnO-CeO2-TiO2 composite oxide was rapidly synthesized by the combustion method using ascorbic acid as combustion agent. The synthesized sample was characterized by XRD, FI-IR, UV-Vis, BET, and SEM. The morphologies and the ultraviolet absorption properties of ZnO-CeO2-TiO2 composite oxide were optimized by changing molar ratio of burning agent, zinc, titanium and cerium ions. The composite oxide exhibits stronger ultraviolet absorption and better photocatalytic properties when mole ratios of burning agent, zinc, titanium, and cerium ions are 8:4:0.25:1. The reason can be attributed to together ZnO, TiO2 with CeO2 degraded and decolorized the methylene blue. The composite oxide shows better decolorizing effect when the molar ratio of burning agent, zinc, titanium, and cerium ions is 8:1:0.25:1. The reason can be attributed to the XRD pattern peak of the composite is completely the same as CeO2, but the composite has better crystalline, so the properties of composite is superior to CeO2.
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