一种改进的夹具,用于量化在使用条件下螺栓法兰垫圈连接的腐蚀

Soroosh Hakimian, L. Hof, H. Bouzid
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摘要

本研究集中于螺栓法兰垫圈连接系统的腐蚀行为。提出了一种新的夹具来量化在使用条件下垫片和法兰之间的腐蚀。根据文献,由于垫圈和法兰之间存在裂缝和潜在的差异,腐蚀广泛发生在这些接缝中。缝隙腐蚀和电偶腐蚀会造成加压流体泄漏,并可能导致灾难性的破坏。先前对螺栓密封接头的腐蚀进行了研究;然而,没有报告操作条件的影响。操作条件包括流体流量、压力、pH值、电导率、温度和垫片接触压力。本研究的第一步是引入一种新的实验装置来检测螺栓法兰垫圈连接的腐蚀行为。开发的装置是一个由加压螺栓垫圈连接组成的夹具,可以实时监控和记录在使用条件影响下的腐蚀参数。第二步,根据ASTM G5进行动电位极化试验,测量腐蚀速率,获得一对法兰和垫片材料腐蚀行为的更多细节。这些测试是使用新设计的装置进行的,该装置再现了工业螺栓法兰垫圈连接系统的行为。它由工作电极(法兰材料)、参比电极(Ag/AgCl)和辅助电极(不锈钢棒)组成。三种类型的石墨垫片被考虑用于电化学测试。腐蚀试验采用0.6 M NaCl溶液。每次测试后,通过共聚焦激光显微镜检查试样的腐蚀表面,分别观察表面上损伤区域的形态和局部腐蚀。
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An Improved Fixture to Quantify Corrosion in Bolted Flanged Gasketed Joints Subjected to Service Conditions
This study concentrates on the corrosion behavior of bolted flanged gasketed joint systems. A novel fixture is proposed to quantify the corrosion between gaskets and flanges under services conditions. According to the literature, due to the presence of crevices and potential differences between gaskets and flanges, corrosion widely occurs in such joints. Crevice corrosion and galvanic corrosion can create paths to leakage of the pressurized fluid and may cause catastrophic failure. Corrosion in bolted gasketed joints was investigated previously; however, the effects of the operating conditions were not reported. Operating conditions include fluid flow, pressure, pH, conductivity, temperature, and gasket contact pressure. The first step of this research study is to introduce a new experimental setup to examine the corrosion behavior of bolted flanged gasketed joints. The developed setup is a fixture that consists of a pressurized bolted gasketed joint that enables real-time monitoring and recording of the corrosion parameters under the influence of service conditions. In the second step, potentiodynamic polarization test is carried out (according to ASTM G5) to measure the corrosion rate and obtain more details on the corrosion behavior of a pair flange and gasket materials. These tests are conducted using the novel designed setup that reproduce the behavior of industrial bolted flanged gasketed joint systems. It consists of a working electrode (flange material), a reference electrode (Ag/AgCl), and an auxiliary electrode (a stainless-steel rod). Three types of graphite gaskets are considered for electrochemical tests. The 0.6 M NaCl solution is used for the corrosion tests. After each test, the corroded surfaces of the specimens are examined via confocal laser microscopy to visualize the morphology of the damaged zones on the surface and localize corrosion, respectively.
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